The gas is in a rigid container: this means that its volume remains constant. Therefore, we can use Gay-Lussac law, which states that for a gas at constant volume, the pressure is directly proportional to the temperature. The law can be written as follows:

Where P1=5 atm is the initial pressure, T1=254.5 K is the initial temperature, P2 is the new pressure and T2=101.8 K is the new temperature. Re-arranging the equation and using the data of the problem, we can find P2:

So, the new pressure is 2 atm.
The rock strike the water with the speed of 15.78 m/sec.
The speed by which rock hit the water is calculated by the formula
v=
v=
v=15.78 m/sec
Hence, the rock strike the water with the speed of 15.78 m/sec.
They seem to cancel each other out which is odd