Answer:
CH3CH2NH3+/CH3CH2NH2 would have the largest pKa
Explanation:
To answer this question we must know Kb of CH3CH2NH2 is 5.6x10⁻⁴, and for C6H5NH2 is 4.0x10⁻¹⁰. And the CH3CH2NH3+ and C6H5NH3+ are related with these substances because are their conjugate base. That means:
pKa of CH3CH2NH3+ = CH3CH2NH2; C6H5NH3+ = C6H5NH2
Also, Kw / Kb = Ka
Thus:
pKa of CH3CH2NH3+/CH3CH2NH2 is:
Kw / kb = Ka = 1.79x10⁻¹¹
-log Ka = pKa
pKa = 10.75
pKa of C6H5NH3+/ C6H5NH2 is:
Kw / kb = Ka = 2.5x10⁻⁵
-log Ka = pKa
pKa = 4.6
That means CH3CH2NH3+/CH3CH2NH2 would have the largest pKa
Answer:
% yield = 82.5%
Explanation:
HgO + 2Cl₂ → HgCl₂ + Cl₂O
Our reactants are:
Our products are:
We do not have information about moles of reactants, but we do know the theoretical yield and the grams of product, in this case Cl₂O, we have produced.
Percent yield = (Yield produced / Theoretical yield) . 100
Theoretical yield is the mass of product which is produced by sufficent reactant. We replace data:
% yield = (0.71 g/0.86g) . 100 = 82.5%
A. We can calculate the initial concentrations of each by
the formula:
initial concentration ci = initial volume * initial
concentration / total mixture volume
where,
total mixture volume = 10 mL + 20 mL + 10 mL + 10 mL = 50
mL
ci (acetone) = 10 mL * 4.0 M / 50 mL = 0.8 M
ci (H+) = 20 mL * 1.0 M / 50 mL = 0.4 M (note: there is only 1 H+ per
1 HCl)
ci (I2) = 10 mL * 0.0050 M / 50 mL = 0.001 M
B. The rate of reaction is determined to be complete when
all of I2 is consumed. This is signified by complete disappearance of I2 color
in the solution. The rate therefore is:
rate of reaction = 0.001 M / 120 seconds
rate of reaction = 8.33 x 10^-6 M / s
Water would not expand when it freezes.<span> </span>
