When it’s warmer so when temperature encreases
Answer:
a. 59 m/atm
Explanation:
- To solve this problem, we must mention Henry's law.
- <em>Henry's law states that at a constant temperature, the amount of a given gas dissolved in a given type and volume of liquid is directly proportional to the partial pressure of that gas in equilibrium with that liquid.</em>
- It can be expressed as: C = KP,
C is the concentration of the solution (C = 1.3 M).
P is the partial pressure of the gas above the solution (P = 0.022 atm).
K is the Henry's law constant (K = ??? M/atm),
∵ C = KP.
∴ K = C/P = (1.3 M)/(0.022 atm) = 59.0 M/atm.
Answer:
Explanation has been given below.
Explanation:
- Chloroform has three polar C-Cl bonds. Methylene chloride has two polar C-Cl bonds. So it is expected that chloroform should be more polar and posses higher dipole moment than methylene chloride.
- Two factors are liable for the opposite trend observed in dipole moments of methylene chloride and chloroform.
- First one is the number of hyperconjugative hydrogen atoms present in a molecule. Hyperconjugation occurs with vacant d-orbital of Cl atom. Hyperconjugation amplifies charge separation in a molecule resulting higher dipole moment.
- Methylene chloride has two hyperconjugative hydrogen atoms and chloroform has one hyperconjugative hydrogen atom.Therefore methylene chloride should have higher charge separation as compared to chloroform.
- Second one is induction of opposite polarity in a C-Cl bond by another C-Cl bond in a molecule. Higher the opposite induction of polarity, lower the charge separation in a molecule and hence lower the dipole moment of a molecule.
- Chloroform has three C-Cl bonds and methylene chloride has two C-Cl bonds. Therefore opposite induction is higher for chloroform resulting it's lower dipole moment.
1 mole of carbon dioxide contains a mass of 44 g, out of which 12 g are carbon.
Hence, in this case the mass of carbon in 8.46 g of CO2:
(12/44) × 8.46 = 2.3073 g
1 mole of water contains 18 g, out of which 2 g is hydrogen;
Therefore, 2.6 g of water contains;
(2/18) × 2.6 = 0.2889 g of hydrogen.
Therefore, with the amount of carbon and hydrogen from the hydrocarbon we can calculate the empirical formula.
We first calculate the number of moles of each,
Carbon = 2.3073/12 = 0.1923 moles
Hydrogen = 0.2889/1 = 0.2889 moles
Then, we calculate the ratio of Carbon to hydrogen by dividing with the smallest number value;
Carbon : Hydrogen
0.1923/0.1923 : 0.2889/0.1923
1 : 1.5
(1 : 1.5) 2
= 2 : 3
Hence, the empirical formula of the hydrocarbon is C2H3
