A student runs an experiment in the lab and then uses the data to prepare an Arrhenius plot of the natural log of the rate const
ant (ln k) versus the inverse of the absolute temperature (1 / T). The general equation of the resulting line is given below. What is the activation energy for the reaction in kilojoules per mole? y = - 2.63 × 103 x + 27.3
The graphical form of the Arrhenius equation is shown on the image attached. Remember that in the Arrhenius equation, we plot the rate constant against the inverse of temperature. The slope of this graph is the activation energy and its y intercept is the frequency factor.
Applying the equation if a straight line, y=mx +c, and comparing the given equation with the graphical form of the Arrhenius equation shown in the image attached, we obtain the activation energy of the reaction as shown.
Water has a higher boiling point because the hydrogen bonds that form water molecules are stronger than the Van der Waals interactions among methane molecules, therefor more energy must be provided in order to break the hydrogen bonds and allow the water molecules to escape the liquid state.