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Ira Lisetskai [31]
3 years ago
14

D) Evaluate your answer and explain why your answer makes sense​

Chemistry
1 answer:
Alik [6]3 years ago
4 0

Answer:

?

Explanation:

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1. If the water is not completely removed from the salt during the heating process will the reported water-to-salt mole ratio (X
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The water in the hydrate (referred to as "water of hydration") can be removed by heating the hydrate. When all hydrating water is removed, the material is said to be anhydrous and is referred to as an anhydrate.

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2 years ago
Calculate the solubilities of the following compounds in a 0.02 M solution of barium nitrate using molar concentrations, first i
Law Incorporation [45]

Answer:

a. 1.7 × 10⁻⁴ mol·L⁻¹; b. 5.5 × 10⁻⁹ mol·L⁻¹

c. 2.3 × 10⁻⁴ mol·L⁻¹;    5.5 × 10⁻⁸ mol·L⁻¹

Explanation:

a. Silver iodate

Let s = the molar solubility.  

                     AgIO₃(s) ⇌ Ag⁺(aq) + IO₃⁻(aq); Ksp = 3.0 × 10⁻⁸

E/mol·L⁻¹:                               s               s

K_{sp} =\text{[Ag$^{+}$][IO$_{3}$$^{-}$]} = s\times s =  s^{2} = 3.0\times 10^{-8}\\s = \sqrt{3.0\times 10^{-8}} \text{ mol/L} = 1.7 \times 10^{-4} \text{ mol/L}

b. Barium sulfate

                     BaSO₄(s) ⇌ Ba²⁺(aq) + SO₄²⁻(aq); Ksp = 1.1 × 10⁻¹⁰

I/mol·L⁻¹:                                0.02             0

C/mol·L⁻¹:                                 +s              +s

E/mol·L⁻¹:                            0.02 + s          s

K_{sp} =\text{[Ba$^{2+}$][SO$_{4}$$^{2-}$]} = (0.02 + s) \times s \approx  0.02s = 1.1\times 10^{-10}\\s = \dfrac{1.1\times 10^{-10}}{0.02} \text{ mol/L} = 5.5 \times 10^{-9} \text{ mol/L}

c. Using ionic strength and activities

(i) Calculate the ionic strength of 0.02 mol·L⁻¹ Ba(NO₃)₂

The formula for ionic strength is  

\mu = \dfrac{1}{2} \sum_{i} {c_{i}z_{i}^{2}}\\\\\mu = \dfrac{1}{2} (\text{[Ba$^{2+}$]}\cdot (2+)^{2} + \text{[NO$_{3}$$^{-}$]}\times(-1)^{2}) = \dfrac{1}{2} (\text{0.02}\times 4 + \text{0.04}\times1)= \dfrac{1}{2} (0.08 + 0.04)\\\\= \dfrac{1}{2} \times0.12 = 0.06

(ii) Silver iodate

a. Calculate the activity coefficients of the ions

\log \gamma = -0.51z^{2}\sqrt{I} = -0.051(1)^{2}\sqrt{0.06} = -0.51\times 0.24 = -0.12\\\gamma = 10^{-0.12} = 0.75

b. Calculate the solubility

AgIO₃(s) ⇌ Ag⁺(aq) + IO₃⁻(aq)

K_{sp} =\text{[Ag$^{+}$]$\gamma_{Ag^{+}}$[IO$_{3}$$^{-}$]$\gamma_{IO_{3}^{-}}$} = s\times0.75\times s \times 0.75 =0.56s^{2}= 3.0 \times 10^{-8}\\s^{2} = \dfrac{3.0 \times 10^{-8}}{0.56} = 5.3 \times 10^{-8}\\\\s =2.3 \times 10^{-4}\text{ mol/L}

(iii) Barium sulfate

a. Calculate the activity coefficients of the ions

\log \gamma = -0.51z^{2}\sqrt{I} = -0.051(2)^{2}\sqrt{0.06} = -0.51\times16\times 0.24 = -0.50\\\gamma = 10^{-0.50} = 0.32

b. Calculate the solubility

BaSO₄(s) ⇌ Ba²⁺(aq) + SO₄²⁻(aq

K_{sp} =\text{[Ba$^{2+}$]$\gamma_{ Ba^{2+}}$[SO$_{4}$$^{2-}$]$\gamma_{ SO_{4}^{2-}}$} = (0.02 + s) \times 0.32\times s\times 0.32 \approx  0.02\times0.10s\\2.0\times 10^{-3}s = 1.1 \times 10^{-10}\\s = \dfrac{1.1\times 10^{-10}}{2.0 \times 10^{-3}} \text{ mol/L} = 5.5 \times 10^{-8} \text{ mol/L}

7 0
3 years ago
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