Answer:
Explanation:
The balanced chemical equation is Cl2 + 2KBr → 2KCl + Br2. The amount of bromine is calculated as follows:
11.0 g KBr (1mol KBr/119.002g KBr * 1mol Br2/2mol KBr * 159.808g Br2/1mol Br2= 7.39 g Br2.)
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1 answer:
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Answer:
See explanation and images attached
Explanation:
a) In the mechanism for the acid catalysed esterification of propanoic acid using ethanol, we can see that the first step is the protonation of the acid followed by nucleophillic attack of the alcohol. Loss of water and consequent deprotonation regenerates the acid catalyst. We can see the fate of the 18O labelled ethanol in the mechanism shown.
b) In the second mechanism, an unnamed ester is hydrolysed using an acid catalyst. The attack of the acid and subsequent nucleophillic attack of water labelled with 18O leads to the incorporation of this 18O into the product acid as shown in the mechanism attached to this answer.
Explanation:
The kinetic energy of translation
m= mass v= linear velocity
The kinetic energy of rotation
I= MOI of the thin walled sphere =kmR^2
where ω= v/R= angular velocity
Then
=1/k
solid sphere: k=0.4; E1/E2 =1/0.4 = 2.5;
hollow sphere: k=2/3; E1/E2 = 1.5
The free energy change(Gibbs free energy-ΔG)=-8.698 kJ/mol
<h3>Further explanation</h3>Given
Ratio of the concentrations of the products to the concentrations of the reactants is 22.3
Temperature = 37 C = 310 K
ΔG°=-16.7 kJ/mol
Required
the free energy change
Solution
Ratio of the concentration : equilbrium constant = K = 22.3
We can use Gibbs free energy :
ΔG = ΔG°+ RT ln K
R=8.314 .10⁻³ kJ/mol K