1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
satela [25.4K]
3 years ago
5

Write a mechanism for the esterification of propanoic acid with 18O-labeled ethanol. Show clearly the fate of the 18O label. (b)

Acid-catalyzed hydrolysis of an unlabeled ester with 18O-labeled water (H218O) leads to incorporation of some 18O into both oxygens of the carboxylic acid product. Explain by a mechanism. (Hint: You must use the fact that all steps in the mechanism are reversible.)
Chemistry
1 answer:
tatuchka [14]3 years ago
5 0

Answer:

See explanation and images attached

Explanation:

a) In the mechanism for the acid catalysed esterification of propanoic acid using ethanol, we can see that the first step is the protonation of the acid followed by nucleophillic attack of the alcohol. Loss of water and consequent deprotonation regenerates the acid catalyst. We can see the fate of the 18O labelled ethanol in the mechanism shown.

b)  In the second mechanism, an unnamed ester is hydrolysed using an acid catalyst. The attack of the acid and subsequent nucleophillic attack of water labelled with 18O leads to the incorporation of this 18O into the product acid as shown in the mechanism attached to this answer.

You might be interested in
which type of cell is a rose thorn A prokaryotic B eukaryota plant C eukaryotic animal D chloroplastic
devlian [24]
Its B Eukatyotic Plant Cell
8 0
3 years ago
Read 2 more answers
PLEASE HELPP ______ consist of one large main root with smaller roots branching off, while _____ consist of several main roots t
Kay [80]

fibrous roots; taproots

Explanation:

A taproot root consists of one large main root with smaller roots that branches off into the soil, while the fibrous roots consists of several main roots that branches off to form one mass of roots.

  • The root system in plants helps them to absorb water and other nutrients from the soil.
  • A taproot is much more like extension of stem that penetrates into the ground.
  • It tapers at the end with many other smaller roots branching and networking from it.
  • The fibrous root is a series of roots directly from the stem that independent of one another.
  • Roots are used by plants for anchorage into the soil.

learn more:

Seedless vascular plants brainly.com/question/6047633

#learnwithBrainly

6 0
3 years ago
Calculate the concentration imports per million ppm of DDT if a sample size of 5000 g contained 0.10 g DDT
nevsk [136]

Answer:

20ppm

Explanation:

parts per million are defined as the mass of solute in mg (In this case, mass of DDT) per kg of sample.

To solve this question we must find the mass of DDT in mg and the mass of sample in kg:

<em>Mass DDT:</em>

0.10g * (1000mg / 1g) = 100mg

<em>Mass sample:</em>

5000g * (1kg / 1000g) = 5kg

Parts per Million:

100mg / 5kg =

<h3>20ppm</h3>
3 0
2 years ago
What is the mass of 0.28 mole of iron?
vredina [299]

Answer:

Your answer should be 15.68 grams.

Explanation:

Seeing as 1 mole has a mass of 56 g, 56*0.28 would get you 15.68 g.

6 0
3 years ago
Adding water to a concentrated stock solution results in the...?
SOVA2 [1]

Answer:

The solution becomes diluted.

Explanation:

When you add water to a solution, the number of moles of the solvent stays the same while the volume increases. Therefore, the molarity decreases.

Hope this helps!

5 0
3 years ago
Other questions:
  • If 2a=3b and a=6 then b=
    5·2 answers
  • Bromocresol green, Ka=2.0×10−5, is yellow in its protonated form (HX) and blue in its ionized form (X−). At what pH will bromocr
    8·1 answer
  • or the solution containing Zn2+(aq), n is 2, so the MM/n ratio will be the molar mass of Zn divided by 2: MM/n = (65.39 g/mol) /
    10·1 answer
  • An bond forms when one atom gives up one or more electrons to another atom
    10·1 answer
  • Salt water is classified as a
    7·2 answers
  • The bond enthalpy in NO is 632 kJ/mol and that of each NO bond in NO2 is 469 kJ/mol. Explain the difference in bond enthalpies b
    9·1 answer
  • What is the percent Nitrogen in Mg(NO2)2?
    12·1 answer
  • How many moles of iron are in 50.0g of iron? How many iron atoms are in 59.0g of iron?
    9·1 answer
  • What is the driving force between chemical reactions between elements
    13·1 answer
  • What is the strongest type of intermolecular force between solute and solvent in each solution? (a) CH3OCH3(g) in H2O(l)
    8·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!