Answer:- The hydroxide ion concentration of the solution is
.
Solution:- The formula used to calculate pOH from hydroxide ion is:
![pOH=-log[OH^-]](https://tex.z-dn.net/?f=pOH%3D-log%5BOH%5E-%5D)
When pOH is given and we are asked to calculate hydroxide ion concentration then we multiply both sides by negative sign and take antilog and what we get on doing this is:
![[OH^-]=10^-^p^O^H](https://tex.z-dn.net/?f=%5BOH%5E-%5D%3D10%5E-%5Ep%5EO%5EH)
pOH is given as 5.71 and we are asked to calculate hydrogen ion concentration. Let's plug in the given value in the formula:
![[OH^-]=10^-^5^.^7^1](https://tex.z-dn.net/?f=%5BOH%5E-%5D%3D10%5E-%5E5%5E.%5E7%5E1)
= 0.00000195 or 
So, the hydroxide ion concentration of the solution is
.
Explanation:
Equation of the reaction:
Br2(l) + Cl2(g) --> 2BrCl(g)
The enthalpy change for this reaction will be equal to twice the standard enthalpy change of formation for bromine monochloride, BrCl.
The standard enthalpy change of formation for a compound,
ΔH°f, is the change in enthalpy when one mole of that compound is formed from its constituent elements in their standard state at a pressure of 1 atm.
This means that the standard enthalpy change of formation will correspond to the change in enthalpy associated with this reaction
1/2Br2(g) + 1/2Cl2(g) → BrCl(g)
Here, ΔH°rxn = ΔH°f
This means that the enthalpy change for this reaction will be twice the value of ΔH°f = 2 moles BrCl
Using Hess' law,
ΔH°f = total energy of reactant - total energy of product
= (1/2 * (+112) + 1/2 * (+121)) - 14.7
= 101.8 kJ/mol
ΔH°rxn = 101.8 kJ/mol.