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weeeeeb [17]
3 years ago
5

Urgent help will be much appreciated

Chemistry
1 answer:
Scorpion4ik [409]3 years ago
6 0

Answer:

b c d a

Explanation:

hgsautaahhttdioirtrf

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Calculate the molar solubility of PbBr2 (Ksp = 4.67x10-6) in 0.10M NaBr solution.
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Explanation:

PbBr_{2} will dissociate into ions as follows.

         PbBr_{2}(s) \rightleftharpoons Pb^{2+}(aq) + 2Br^{-}(aq)

Hence, K_{sp} for this reaction will be as follows.

                   K_{sp} = [Pb^{2+}][Br^{-}]^{2}

We take x as the molar solubility of PbBr_{2} when we dissolve x moles of solution per liter.

Hence, ionic molarities in the saturated solution will be as follows.

               [Pb^{2+}] = [Pb^{2+}]_{o} + x

               [Br^{-}]^{2} = [Br^{-}]_{o} + 2x

So, equilibrium solubility expression will be as follows.

            K_{sp} = ([Pb^{2+}]_{o} + x)([Br^{-}]_{o} + 2x)^{2}

Each sodium bromide molecule is giving one bromide ion to the solution. Therefore, one solution contains [Br^{-}]_{o} = 0.10 and there will be no lead ions. So, [Pb^{2+}]_{o} = 0

So, [Br^{-}]_{o} + 2x will approximately equals to [Br^{-}]_{o}.

Hence, K_{sp} = x[Br^{-}]^{2}_{o}

            4.67 \times 10^{-6} = x \times (0.10)^{2}

                        x = 4.67 \times 10^{-4} M

Thus, we can conclude that molar solubility of PbBr_{2} is 4.67 \times 10^{-4} M.

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