First, let's compute the number of moles in the system assuming ideal gas behavior.
PV = nRT
(663 mmHg)(1atm/760 mmHg)(60 L) = n(0.0821 L-atm/mol-K)(20+273 K)
Solving for n,
n = 2.176 moles
At standard conditions, the standard molar volume is 22.4 L/mol. Thus,
Standard volume = 22.4 L/mol * 2.176 mol =<em> 48.74 L</em>
Since the sign is positive, the entropy increased by 88.48 J/K.
Examine the phases of the species present to determine whether a physical or chemical process will cause an increase or decrease in entropy. Keep in mind "Silly Little Goats" to aid you in telling.
[1 Sf K+1 + 1 Sf Br-1 (aq)] ([1Sf(KBr (s))])
[1(102.5) + 1(82.42)] - [1(96.44)] = 88.48 J/K
If the entropy has grown, we say that Delta S is positive, and if it has dropped, we say that Delta S is negative. Due to its ionic nature, KBr is soluble in water and causes the 'K(+)' ions to hydrate.
Learn more about Entropy here-
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What are your answer choices? Scientists express the weight in AMU’s so that they can easily think about the weight of the atom. If it is expressed in grams, they’re constantly dealing with a weight that’s around 10^-24 grams, which is hard to deal with.
