Question

Complete and balance the following redox reaction in basic solution

Answer 1

Answer:

balanced in ACID not BASE

Cr2O7^2-(aq) +3Hg(l) +14 H^1+ ----> 3Hg^2+ + 2Cr^3+(aq) + 7H2O

Answer

Cr2O7^2-(aq) +3Hg(l) +14 H^1+ ----> 3Hg^2+ + 2Cr^3+(aq) + 7H2O

Explanation:

Cr2O7^2-(aq) + Hg(l) ----> Hg^2+(aqH) + Cr^3+(aq)

add H^1+ (acid) to capture the O and make 7 water molecules

Cr2O7^2-(aq) + Hg(l) + H^1+ ----> Hg^2+(aqH) + Cr^3+(aq) + 7H2O

Cr goes from +6 to +3 by gaining 3 e

Hg goes from 0 to +2 by losing 2 e

we need 3 Hg for every 2 Cr

so

Cr2O7^2-(aq) +3Hg(l) +14 H^1+ ----> 3Hg^2+ + 2Cr^3+(aq) + 7H2O

2 Cr on the right and left

Net 12 positive charges on the right and the left

3 Hg on the right and left

14 H on the right and left

the equation is balanced

we cannot balance the equation in a basic solution with OH^1-

we have plenty of O in the dichromate ion. we need to convert it to water which take free H^1+ from the acid