Answer:
The molecular formula of cacodyl is C₄H₁₂As₂.
Explanation:
<u>Let's assume we have 1 mol of cacodyl</u>, in that case we'd have 209.96 g of cacodyl and the<u> following masses of its components</u>:
- 209.96 g * 22.88/100 = 48.04 g C
- 209.96 g * 5.76/100 = 12.09 g H
- 209.96 g * 71.36/100 = 149.83 g As
Now we convert those masses into moles:
- 48.04 g C ÷ 12 g/mol = 4.00 mol C
- 12.09 g H ÷ 1 g/mol = 12.09 mol H
- 149.83 g As ÷ 74.92 g/mol = 2.00 mol As
Those amounts of moles represent the amount of each component in 1 mol of cacodyl, thus, the molecular formula of cacodyl is C₄H₁₂As₂.
These rocks were either roasted or exposed to severe weathering
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Answer:
To fulfill octet of B atom in borane, nucleophilic attack by pi electrons of alkene takes place with electrophilic B center in borane.
Explanation:
In Borane (
), B atom has energetically vacant 2p orbital and thereby octet is incomplete.Therefore B center in borane act as an electrophilic center.
In alkene, pi bonding electrons are loosely bound together due to side on overlap of two constituent p-orbitals. Hence this pi bond can be easily broken. Alternatively, we can say that pi bond in alkene act as a potential nucleophile.
The first step of hydroboration occurs in a concerted manner where pi electrons of alkene first attack vacant 2p orbital of B in borane to fulfill it's octet (represented by an arrow drawn from alkene to B atom) and forms a 4 memebered cyclic intermediate. Simulaneously, a B-H bond in borane is donated to alkene through 3c-2e bond (3 center-2 electron bond).
Full mechanism has been shown below.