Answer:
Reagent A = 
Reagent B= 
Intermediate C= δ-Valerolactone
Explanation:
In the reaction from the alkene to the alcohol, we can use the <u>alkene hydration</u> in which the hydronium ion is added to the double bond followed by the attack of water to produce the <u>alcohol</u>.
Then in the conversion from alcohol to ketone can be produced if an <u>oxidant reactive</u><u> </u>is used. In this case the <u>Jones reagent </u>( ).
The intermediate is a structure produced by a <u>peroxyacid</u>. This reaction would introduce an <u>ester group </u>in the cycle generating the δ-Valerolactone (Figure 1).
Answer:
See explanation and image attached
Explanation:
Aromatic hydrocarbons undergo electrophillic substitution. Usually, substituted benzene is more or less reactive to electrophillic substitution compared to unsubstituted benzene.
Substituents on the benzene ring tend to direct the incoming electrophile during electrophillic substititution. The presence of the -CH3 group on toluene directs the incoming Br electrophile to the ortho/para position.
Where the incoming electrphile E is Bromine, we can see that in the ortho/ para product, the electron pushing -CH3 stabilizes the resonance structure formed and increases electron density at the ortho/para position via resonance compared to the meta product as we can see from the image attached. Hence, the ortho and para products predominate over meta products.
Image credit: Chemistry steps
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Molality= mol/ Kg
if we assume that we have 1 kg of water, we have 3.19 moles of solute.
the formula for mole fraction --> mole fraction= mol of solule/ mol of solution
1) if we have 1 kg of water which is same as 1000 grams of water.
2) we need to convert grams to moles using the molar mass of water
molar mass of H₂O= (2 x 1.01) + 16.0 = 18.02 g/mol
1000 g (1 mol/ 18.02 grams)= 55.5 mol
3) mole of solution= 55.5 moles + 3.19 moles= 58.7 moles of solution
4) mole fraction= 3.19 / 58.7= 0.0543
Answer:
-255.4 kJ
Explanation:
The free energy of a reversible reaction can be calculated by:
ΔG = (ΔG° + RTlnQ)*n
Where R is the gas constant (8.314x10⁻³ kJ/mol.K), T is the temperature in K, n is the number of moles of the products (n =1), and Q is the reaction quotient, which is calculated based on the multiplication of partial pressures by the partial pressure of the products elevated by their coefficient divide by the multiplication of the partial pressure of the reactants elevated by their coefficients.
C₂H₂(g) + 2H₂(g) ⇄ C₂H₆(g)
Q = pC₂H₆/[pC₂H₂ * (pH₂)²]
Q = 0.261/[8.58*(3.06)²]
Q = 3.2487x10⁻³
ΔG = -241.2 + 8.314x10⁻³x298*ln(3.2487x10⁻³)
ΔG = -255.4 kJ
