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Juli2301 [7.4K]
3 years ago
5

A compound consists of 75% magnesium and 25% oxygen. Find the empirical formula.

Chemistry
1 answer:
laila [671]3 years ago
8 0
<h2>Answer:</h2>

% Composition of elements:

  • Magnesium = 75%
  • Oxygen = 25%

Atomic mass of given elements:

  • Magnesium = 24 g
  • Oxygen = 16 g

Now, divide % composition by Atomic mass:

\footnotesize\implies Mg = \dfrac{\% \:  Composition}{Atomic  \: mass} =  \dfrac{75}{24}  =  \bf 3.125

\footnotesize\implies O = \dfrac{\% \:  Composition}{Atomic  \: mass} =  \dfrac{25}{16}  =  \bf 1.5625

Simplest Ratio:

\footnotesize\implies Mg  =  \dfrac{3.125}{1.5625}  = 2

\footnotesize\implies O  =  \dfrac{1.5625}{1.5625} = 1

Empirical Formula:

\footnotesize\implies \underline{ \boxed{ \red{ \bf Empirical \:  Formula = Mg_2O}}}

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Answer : The entropy change for the surroundings of the reaction is, -198.3 J/K

Explanation :

We have to calculate the entropy change of reaction (\Delta S^o).

\Delta S^o=S_{product}-S_{reactant}

\Delta S^o=[n_{NH_3}\times \Delta S^0_{(NH_3)}]-[n_{N_2}\times \Delta S^0_{(N_2)}+n_{H_2}\times \Delta S^0_{(H_2)}]

where,

\Delta S^o = entropy of reaction = ?

n = number of moles

\Delta S^0{(NH_3)} = standard entropy of NH_3

\Delta S^0{(H_2)} = standard entropy of H_2

\Delta S^0{(N_2)} = standard entropy of N_2

Now put all the given values in this expression, we get:

\Delta S^o=[2mole\times (192.5J/K.mole)]-[1mole\times (191.5J/K.mole)+3mole\times (130.6J/K.mole)]

\Delta S^o=-198.3J/K

Therefore, the entropy change for the surroundings of the reaction is, -198.3 J/K

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3 years ago
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Name two compounds with more exothermic lattice energies than scandium oxide and justify your choice.
N76 [4]

Answer:

1 . Al_2O_3

2. TiO_2

Explanation:

The more stable the ionic compound, the more is it lattice energy.

  • The more the charge on the cation and the anion, the greater is the lattice energy.
  • The less the size of the cation and the anion, the greater is the lattice energy.

Scandium oxide (Sc_2O_3) is an oxide in which Sc^{3+} behaves as cation and O^{2-} behaves as anion.

The compounds which has higher lattice energy than scandium oxide are:

1 . Al_2O_3

This is because the charge are same on the cation and the anion as in the case of the Scandium oxide but the size of the cation Al^{3+} is smaller than Sc^{3+}. Thus, this corresponds to higher lattice energy.

2. TiO_2

This is because the charge on the cation Ti^{4+} is greater than that of Sc^{3+} and also the size of the cation Ti^{4+} is smaller than Sc^{3+}. Thus, this corresponds to higher lattice energy.

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