Answer:
Enthalpy change for the reaction is -67716 J/mol.
Explanation:
Number of moles of
in 50.0 mL of 0.100 M of 
= Number of moles of HCl in 50.0 mL of 0.100 M of HCl
=
moles
= 0.00500 moles
According to balanced equation, 1 mol of
reacts with 1 mol of HCl to form 1 mol of AgCl.
So, 0.00500 moles of
react with 0.00500 moles of HCl to form 0.00500 moles of AgCl
Total volume of solution = (50.0+50.0) mL = 100.0 mL
So, mass of solution = (
) g = 100 g
Enthalpy change for the reaction = -(heat released during reaction)/(number of moles of AgCl formed)
=
= ![\frac{-100g\times 4.18\frac{J}{g.^{0}\textrm{C}}\times [24.21-23.40]^{0}\textrm{C}}{0.00500mol}](https://tex.z-dn.net/?f=%5Cfrac%7B-100g%5Ctimes%204.18%5Cfrac%7BJ%7D%7Bg.%5E%7B0%7D%5Ctextrm%7BC%7D%7D%5Ctimes%20%5B24.21-23.40%5D%5E%7B0%7D%5Ctextrm%7BC%7D%7D%7B0.00500mol%7D)
= -67716 J/mol
[m = mass, c = specific heat capacity,
= change in temperature and negative sign is included as it is an exothermic reaction]
Answer:
A and D are true , while B and F statements are false.
Explanation:
A) True. Since the standard gibbs free energy is
ΔG = ΔG⁰ + RT*ln Q
where Q= [P1]ᵃ.../([R1]ᵇ...) , representing the ratio of the product of concentration of chemical reaction products P and the product of concentration of chemical reaction reactants R
when the system reaches equilibrium ΔG=0 and Q=Keq
0 = ΔG⁰ + RT*ln Q → ΔG⁰ = (-RT*ln Keq)
therefore the first equation also can be expressed as
ΔG = RT*ln (Q/Keq)
thus the standard gibbs free energy can be determined using Keq
B) False. ΔG⁰ represents the change of free energy under standard conditions . Nevertheless , it will give us a clue about the ΔG around the standard conditions .For example if ΔG⁰>>0 then is likely that ΔG>0 ( from the first equation) if the temperature or concentration changes are not very distant from the standard conditions
C) False. From the equation presented
ΔG⁰ = (-RT*ln Keq)
ΔG⁰>0 if Keq<1 and ΔG⁰<0 if Keq>1
for example, for a reversible reaction ΔG⁰ will be <0 for forward or reverse reaction and the ΔG⁰ will be >0 for the other one ( reverse or forward reaction)
D) True. Standard conditions refer to
T= 298 K
pH= 7
P= 1 atm
C= 1 M for all reactants
Water = 55.6 M
It is energetically favorable for all atoms to have a complete outer
electron shell. Loosely, the atoms on the left hand side of the periodic
table only have a few extra electrons in their outer shell so it is
energetically favorable for them to lose them. The atoms on the right
hand side of the periodic table almost have enough electrons in their
outer shell and so they have a tendency to gain them.
Once electrons have left an electron shell, an atom will have a positive
charge because it has more protons (positive charges) than electrons
(negative charges). Similarly, an electron which has gained electrons to
complete its outer shell will have a negative charge because it now has
more electrons (negative charge) than protons (positive charge).
The answer is B for the apex answer
To work out the kinetic energy of an object, you use the formula:
E = 0.5 x (mass) x (velocity)^2
One important thing, though. The units MUST be consistent. Mass needs to be in kilograms, and velocity in metres per second.
To convert the mass form grams to kilograms, we need to divide it by 1000, getting 0.0103 kg. Since the velocity is already in the units we need, we can just plug the numbers into the equation to get:
E = 0.5 x (0.0103 kg) x (48.0)^2 = 11.8656 J = 11.9 J, to 3 significant figures
Hope I helped! xx