4.1 h = 14760 s
<span>t 1/2 = ln 2 / k </span>
<span>k = rate reaction = 4.97 x 10^-5 </span>
<span>ln 0.045 / 0.36 = - 4.97 x 10^-5 t </span>
<span>2.08 = 4.97 x 10^-5 t </span>
<span>t = 41839.9 s = 11 h 37 min 19 s</span>
For the purpose we will use solution dilution equation:
c1xV1=c2xV2
Where, c1 - concentration of stock solution; V1 - a volume of stock solution needed to make the new solution; c2 - final concentration of new solution; V2 - final volume of new solution.
c1 = 5.00 M
c2 = 0.45 M
V1 = ?
V2 = 108 L
When we plug values into the equation, we get following:
5 x V1 = 0.45 x 108
<span>V1 = </span>9.72 L