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Answer : The value of for this reaction is 36.18 kJ
Explanation :
First law of thermodynamic : It states that the energy can not be created or destroyed, it can only change or transfer from one state to another state.
As per first law of thermodynamic,
where,
= internal energy of the system
q = heat added or rejected by the system
w = work done
As we are given that:
q = 38.65 kJ
w = -2.47 kJ (system work done on surrounding)
Now put all the given values in the above expression, we get:
Therefore, the value of for this reaction is 36.18 kJ
Note the signs of equilibrium:-
- Reaction don't procede forward or backward
- Concentration of products and reactants remains same .
So
if
Concentration of A is 2M then concentration of B should be same .
So equilibrium constant K is 1
So
- [B]=[A]^2
- [B]=2^2
- [B]=4M