Answer : The value of change in entropy for freezing process is, -18.07 J/mol.K
Explanation :
Formula used :

where,
= change in entropy
= change in enthalpy of fusion = 3.17 kJ/mol
As we know that:

= freezing point temperature = 
Now put all the given values in the above formula, we get:



Therefore, the value of change in entropy for freezing process is, -18.07 J/mol.K
Grams of Phosphorus = 4.14 grams
Grams of white compound = 27.8 grams
Grams of Chlorine would be = 27.8 - 4.14 = 23.66 grams
Calculating moles which would be grams / molar mass
Molar mass of P = 30.97 grams / moles; Molar mass of Cl = 35.45 grams / moles
Moles of Phosphorus = 4.14 grams / 30.97 grams / moles = 0.1337 moles
Moles of Chlorine = 23.66 grams / 35.45 grams / moles = 0.6674 moles
Calculating the ratios by dividing with the small entity
P = 0.1337 moles / 0.1337 moles = 1
Cl = 0.6674 moles / 0.1337 moles = 5
So the empirical formula would be PCl5
To answer the question that is: "which factors affect a river's load", we have to understand that all the things mentioned are important. All these options (river's slope, streambed shape and volume of flow) affect the amount of energy that the river has to spend and the way the river spend that energy, so, it is right to mark the alternative <span>d) all of the above.</span>