Answer:
ΔG = - 590.20 kJ/mol
Explanation:
The formula for calculating Gibb's Free Energy can be written as:
ΔG = ΔH - TΔS
Given That:
ΔH = -720.5 kJ/mol
T = 221.0°C = (221.0 + 273.15) = 494.15 K
ΔS° = -263.7 J/K
So; ΔS° = -0.2637 kJ/K if being converted from joule to Kilo-joule
Since we are all set, let replace our given data in the above equation:
ΔG = (-720.5 kJ/mol) - (494.15 K) ( - 0.2637 kJ/K)
ΔG = (-720.5 kJ/mol) - (- 130.30755)
ΔG = -720.5 kJ/mol + 130.30755
ΔG = -590.192645 kJ/mol
ΔG = - 590.20 kJ/mol
Thus, The value of ΔG° at 221.0°C for the formation of phosphorous trichloride from its constituent elements, P2(g) + 3Cl2(g) → 2PCl3(g) is <u>-590.20</u> kJ/mol.
The product of molarity and volume of any substance at a fixed temperature is constant. Therefore comparing two portions of different molarity, we can say that, M₁V₁=M₂V₂
M represents the molarity, V represents volume of the solution.
M₁ in the question is 8.8M
M₂ is 2.2M
V₁=?
V₂= 175
therefore,
8.8ₓV₁= 2.2ₓ175ml
V₁=(2.2ₓ175ml)/8.8
=43.75 ml
Answer:
a. 2.44 nm
b. 15.33 nm²
Explanation:
a. Calculate the thickness (in nm) of the surface film
Since the volume of a teaspoon equals V = 4.93 cm³ and the area of the oil film is half an acre = 1/2 × 4046.86 m² = 2023.43 m²
The volume of the oil film, V' equals the volume of the oil in the teaspoon, V
V' = Ah where A = cross-sectional area of oil film = 2023.43 m² = 2023.43 × 10⁴ cm² and h = height of oil film
So, V' = V
Ah = V
h = V/A
= 4.93 cm³/2023.43 × 10⁴ cm²
= 0.00244 × 10⁻⁴ cm
= 2.44 × 10⁻⁷ cm
= 2.44 × 10⁻⁷ cm × 1m/100 cm
= 2.44 × 10⁻⁹ m
= 2.44 nm
b. The surface area (in nm2) occupied by an oleic acid molecule on water.
Since the height of the oil film equals the diameter of the oil molecule, and the molecule is assumed to be a sphere of radius, r. Its surface area is thus A = 4πr²
r = h/2 = 2.44 nm/2 = 1.22 nm
A = 4πr²
A = 4π(1.22 nm)²
A = 4.88π nm²
A = 15.33 nm²
