The correct answer is a. This is because the pH of a solution is defined as -log10(concentration of H+ ions). An inverse logarithmic scale such as this means that a solution with a lower concentration of H+ ions will have a higher pH than one with a higher concentration. Therefore we know that the pH of the second sample will be higher than the first.
Since the logarithmic scale has the base 10, a change by 1 on the scale is a consequence of multiplication/division of the H+ concentration by a factor of 10. As the scale is inverse, this means that a decrease of concentration by factor 1000 is equivalent to increasing the pH by (1000/10) = 3.
The answer is number 4 or the exchange of energy with the surroundings. Calorimetry is a measurement of energy that is formed or absorbed in a certain process. The calorimeter is the instrument used in order to measure the energy. It is recommended that a calorimeter should be a closed system so as to measure precisely the energy and avoid or lessen the exchange of energy with the surroundings. Thus, comparing an open ceramic mug and an insulated mug with a lid, the greatest difference is the energy lost to the surroundings.
The answer would be ethane (C2H4)
Answer:
[OH⁻] = 4.3 x 10⁻¹¹M in OH⁻ ions.
Explanation:
Assuming the source of the carbonate ion is from a Group IA carbonate salt (e.g.; Na₂CO₃), then 0.115M Na₂CO₃(aq) => 2(0.115)M Na⁺(aq) + 0.115M CO₃²⁻(aq). The 0.115M CO₃²⁻ then reacts with water to give 0.115M carbonic acid; H₂CO₃(aq) in equilibrium with H⁺(aq) and HCO₃⁻(aq) as the 1st ionization step.
Analysis:
H₂CO₃(aq) ⇄ H⁺(aq) + HCO₃⁻(aq); Ka(1) = 4.3 x 10⁻⁷
C(i) 0.115M 0 0
ΔC -x +x +x
C(eq) 0.115M - x x x
≅ 0.115M
Ka(1) = [H⁺(aq)][HCO₃⁻(aq)]/[H₂CO₃(aq)] = [(x)(x)/(0.115)]M = [x²/0.115]M
= 4.3 x 10⁻⁷ => x = [H⁺(aq)]₁ = SqrRt(4.3 x 10⁻⁷ · 0.115)M = 2.32 x 10⁻⁴M in H⁺ ions.
In general, it is assumed that all of the hydronium ion comes from the 1st ionization step as adding 10⁻¹¹ to 10⁻⁷ would be an insignificant change in H⁺ ion concentration. Therefore, using 2.32 x 10⁻⁴M in H⁺ ion concentration, the hydroxide ion concentration is then calculated from
[H⁺][OH⁻] = Kw => [OH⁻] = (1 x 10⁻¹⁴/2.32 x 10⁻⁴)M = 4.3 x 10⁻¹¹M in OH⁻ ions.
________________________________________________________
NOTE: The 2.32 x 10⁻⁴M value for [H⁺] is reasonable for carbonic acid solution with pH ≅ 3.5 - 4.0.
