CH4 is an emprirical formula as it shows the simplest ratio of the numbers of different atoms present in the molecule. The empirical formula for CH4 is also the same as the molecular formula.
The other compunds can be simplified so they are not the empirical formula of compounds.
Hope this helps :).
Answer: -
12.41 g
Explanation: -
Mass of CO₂ = 42 g
Molar mass of CO₂ = 12 x 1 + 16 x 2 = 44 g / mol
Number of moles of CO₂ = 
= 0.9545 mol
The balanced chemical equation for this process is
2C₆H₆ + 15O₂ → 12CO₂ + 6H₂O
From the balanced chemical equation we see
12 mol of CO₂ is produced from 2 mol of C₆H₆
0.9545 mol of CO₂ is produced from 
= 0.159 mol of C₆H₆
Molar mass of C₆H₆ = 12 x 6 + 1 x 6 =78 g /mol
Mass of C₆H₆ =Molar mass x Number of moles
= 78 g / mol x 0.159 mol
= 12.41 g
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