Answer: ![-\frac{1}{2}\times \frac{d[Br^.]}{dt}=+\frac{d[Br_2]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7B1%7D%7B2%7D%5Ctimes%20%5Cfrac%7Bd%5BBr%5E.%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D)
Explanation:
Rate of a reaction is defined as the rate of change of concentration per unit time.
Thus for reaction:

The rate in terms of reactants is given as negative as the concentration of reactants is decreasing with time whereas the rate in terms of products is given as positive as the concentration of products is increasing with time.
![Rate=-\frac{d[Br^.]}{2dt}](https://tex.z-dn.net/?f=Rate%3D-%5Cfrac%7Bd%5BBr%5E.%5D%7D%7B2dt%7D)
or ![Rate=+\frac{d[Br_2]}{dt}](https://tex.z-dn.net/?f=Rate%3D%2B%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D)
Thus ![-\frac{d[Br^.]}{2dt}=+\frac{d[Br_2]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7Bd%5BBr%5E.%5D%7D%7B2dt%7D%3D%2B%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D)
Explanation:
(a)
Critical angle is the angle at the angle of refraction is 90°. After the critical angle, no refraction takes place.
Using Snell's law as:
Where,
is the angle of incidence
is the angle of refraction = 90°
is the refractive index of the refraction medium
is the refractive index of the incidence medium
Thus,
The formula for the calculation of critical angle is:
Where,
is the critical angle
(b)
No it cannot occur. It only occur when the light ray bends away from the normal which means that when it travels from denser to rarer medium.
Answer:

Explanation:
h = Planck's constant = 
c = Speed of light = 
E = Energy = 
Wavelength ejected is given by

The maximum wavelength in angstroms of the radiation that will eject electrons from the metal is 
Answer: Limiting reactant
Explanation:
The limiting reactant is a reactant will get completely consumed up in the reaction. This reactant being in low concentration will lead to the formation of limited amount of product.
In the given situation, since the butter cakes are required to be 3 sticks for making 3 cakes but only 2 cakes are available thus the butter stick is the limiting reactant.