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AlladinOne [14]
3 years ago
11

(a) Sketch, in a cubic unit cell, a [111] and a [112] lattice direction. (b) Use a trigonometric calculation to determine the an

gle between these two directions. (c) Use Equation 3.3 to determine the angle between these two directions.

Chemistry
1 answer:
fgiga [73]3 years ago
7 0

Answer and Explanation:

a) The direction is shown in the cube diagram attached to this solution.

b) the angle between two planes (h₁, k₁, l₁) and (h₂, k₂, l₂) is given by the formula,

Cos Φ = (h₁h₂ + k₁k₂ + l₁)/√((h₁² + k₁² + l₁²)(h₂² + k₂² + l₂²))

For (111) and (112)

Cos Φ = (1.1 + 1.1 + 1.2)/√((1² + 1² + 1²)(1² + 1² + 2²))

Cos Φ = (1 + 1 + 2)/√((1+1+1)(1+1+4))

Cos Φ = 4/√(3×6)

Cos Φ = 4/√18

Φ = cos⁻¹ (4/√18) = 19.56°

c) equation 3.3 is missing from the question, I would be back to provide the answers to that as soon as the equation is provided!

Hope this Helps!!

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Answer:

See explanation and images attached

Explanation:

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What total volume of ozone measured at a pressure of 24.5 mmHg and a temperature of 232 K can be destroyed when all of the chlor
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Answer:

1.75272\ \text{m}^3

Explanation:

The breakdown reaction of ozone is as follows

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M = Molar mass of CF_3Cl = 104.46 g/mol

P = Pressure = 24.5 mmHg

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R = Gas constant = 62.363\ \text{L mmHg/K mol}

Number of moles is given by

n=\dfrac{m}{M}\\\Rightarrow n=\dfrac{15.5}{104.46}\\\Rightarrow n=0.1484\ \text{moles}

20\ \text{moles} = 20\times 0.1484 = 2.968\ \text{moles}

From ideal gas law we have

PV=nRT\\\Rightarrow V=\dfrac{nRT}{P}\\\Rightarrow V=\dfrac{2.968\times 62.363\times 232}{24.5}\\\Rightarrow V=1752.72\ \text{L}=1.75272\ \text{m}^3

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