Answer:
See explanation and images attached
Explanation:
a) In the mechanism for the acid catalysed esterification of propanoic acid using ethanol, we can see that the first step is the protonation of the acid followed by nucleophillic attack of the alcohol. Loss of water and consequent deprotonation regenerates the acid catalyst. We can see the fate of the 18O labelled ethanol in the mechanism shown.
b) In the second mechanism, an unnamed ester is hydrolysed using an acid catalyst. The attack of the acid and subsequent nucleophillic attack of water labelled with 18O leads to the incorporation of this 18O into the product acid as shown in the mechanism attached to this answer.
Answer:

Explanation:
The breakdown reaction of ozone is as follows




It can be seen that 2 moles of ozone is required in the complete cycle
So for 10 cycles, 20 moles of ozone is required
m = Mass of
= 15.5 g
M = Molar mass of
= 104.46 g/mol
P = Pressure = 24.5 mmHg
T = Temperature = 232 K
R = Gas constant = 
Number of moles is given by


From ideal gas law we have

For 20 cycles of the reaction the volume of the ozone is
.
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