If I have 4 moles of a gas at a pressure of 5.6 atm and a volume of 12 liters, what is the temperature? (2005 K)
1 answer:
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Answer:
Z* = 3.55
Explanation:
Slater rule says that:
Z*= Z - S
Z* be the nuclear effective charge
Z is the nuclear charge
S is the shielding constant
First we write the electronic configuration of platinum:
The first Slater rule says that we need to group:
The second rule says that the electrons to the right are not shielding, but we are going to solve the exercise for the last level (6s), so we don't have electrons to the right.
For the third rule we have two considerations, if is ns or np and if is nd or nf:
For our case, we have an electro that is in ns, so the rule says that
-electrons within same group shield 0.35, except the 1s which shield 0.30
-electrons within the n-1 group shield 0.85
-electrons within the n-2 or lower groups shield 1.00
Now we can proceed with the calculation:
The first consideration in the third rule does not apply as we only have one electron on this level.
The second consideration will be as follow for the level 5, where we have 17 electrons.
Finally the third consideration will be for levels 1, 2, 3 and 4, where we have 14 for 4f, 10 for 4d, 8 for 4s and 4p, 10 for 3d, 8 for 3s and 3p, 8 for 2s and 2p and finally 2 for 1s, which gives 60 electrons.
So the result for S=(60*1.00 + 17*0.85) = 74.45
And the equation is: Z* = 78 - 74.45
So Z* = 3.55
Answer:
See answer below
Explanation:
First, let's explain what a Lewis structure is.
A lewis structure in short words is a draw of an atom or molecule showing how the electrons bond with another electrons of atoms, and also shows the unshared pair of electrons, which are the electrons that do not bond in the molecule. In the case of an atom, it shows all the available electrons it has to be shared and bonded with another atom to form a molecule.
With this said, in order to draw the lewis structure we need to know how many electrons the atoms involved have. To know this, we need to write the electronic configuration of the atoms, based on it's atomic number.
In the case of Hydrogen (Z = 1), Carbon (Z = 6) and Cl (Z = 17):
[H] = 1s¹ 1 electron available.
[C] = 1s² 2s² 2p² In this case, we have 4 electrons.
[Cl] = 1s² 2s² 2p⁶ 3s² 3p⁵ In this case, 7 electrons.
Now that we have the configuration, and the available electrons, we need to draw the atoms. The Carbon is the more electronegative atom of them, so, the bonding will be formed based on this atom as the central. So the other atoms will just bond and shared a pair of electron with the carbon. The HCCl₃ can be treated as CH₄, with a tetrahedrical form.
The picture below shows the lewis structure.
Hope this helps
Answer:
Ethanol most easily forms hydrogen bonds.
Explanation:
The difference among the alcohols in this question is the size of carbonic chain and the position of the -OH group.
Ethanol has 2 carbons and the -OH group is terminal. The other alcohols have more carbons and the -OH group is not terminal. This means that the approximation of molecules will be facilitated for ethanol, and the interaction through hydrogen bons will be easier. However, for the other molecules, there will be steric hindrance, which will make it more difficult for the molecules to make hydrogen bonds.
The figure attached shows the alcohol structures.
