Answer:
SN2
Explanation:
The first step of ether cleavage is the protonation of the ether since ROH is a better leaving group than RO-.
The second step of the reaction may proceed by either SN1 or SN2 mechanism depending on the structure of the ether. Methyl and primary ethers react with HI by SN2 mechanism while tertiary ethers react with HI by SN1 mechanism. Secondary ethers react with HI by a mixture of both mechanisms.
Dipentyl ether is a primary ether hence when treated with HI, the reaction with HI proceeds by SN2 mechanism as explained above.
Answer:
Step 1;
q = w = -0.52571 kJ, ΔS = 0.876 J/K
Step 2
q = 0, w = ΔU = -7.5 kJ, ΔH = -5.00574 kJ
Explanation:
The given parameters are;
= 100 N·m
= 327 K
= 90 N·m
Step 1
For isothermal expansion, we have;
ΔU = ΔH = 0
w = n·R·T·ln(
/
) = 1 × 8.314 × 600.15 × ln(90/100) = -525.71
w ≈<em> -0.52571</em> kJ
At state 1, q = w = -0.52571 kJ
ΔS = -n·R·ln(
/
) = -1 × 8.314 × ln(90/100) ≈ 0.876
ΔS ≈ 0.876 J/K
Step 2
q = 0 for adiabatic process
ΔU = 25×(27 - 327) = -7,500
w = ΔU = <em>-7.5 kJ</em>
ΔH = ΔU + n·R·ΔT
ΔH = -7,500 + 8.3142 × 300 = -5,005.74
ΔH = ΔU = <em>-5.00574 kJ</em>
Answer:
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Answer: A.
Explanation:
Gravitational potential energy is due to the position of an object above Earth's surface. The object has the potential to fall due to gravity. Gravitational potential energy depends on an object's weight and its height above the ground (GPE = weight x height).
Weight= Mass
Height= Height
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