Answer:
a. Xm = 0.0229
b. 0.0234 moles
c. 354.1 g/mol
Explanation:
ΔP = P° . Xm
ΔP = P° - P', where P° is vapor pressure of pure solvent and P', vapor pressure of solution-
This is the formula for lowering vapor pressure.
If we apply the data given: 523 Torr - 511 Torr = 523 . Xm
Xm = ( 523 Torr - 511 Torr) / 523 Torr → 0.0229
Xm = Mole fraction of solute → Moles of solute / Total moles (sv + solute)
We can make this equation to determine moles of solute
0.0229 = Moles of solute / Moles of solute + 1
0.0229 (Moles of solute + 1) = Moles of solute
0.0229 = Moles of solute - 0.0229 moles of solute
0.0229 = 0.9771 moles of solute → 0.0229 / 0.9971 = 0.0234 moles
Molecular mass of solute → g/mol → 8.3 g / 0.0234 mol = 354.1 g/mol
Lowery-Bronsted theory is applied here. Acc. to this theory Base accepts protons and Acids donate proton.
Part 1:
Aniline is less basic than ethylamine because the lone pair on nitrogen (which accepts proton) is not localized. It resonates throughout the conjugated system of phenyl ring. Hence due to unavailability of electrons for accepting proton it is less basic compare to ethylamine. In ethyl amine the lone pair of electron is localized and available to abstract proton.
Part 2:
In this case the alkyl groups attached to -NH₂ (in ethylamine) and -O⁻ (in ethoxide are same (i.e. CH₃-CH₂-). Ethoxide is more basic than ethylamine because ethoxide is a conjugate base of ethanol (pKa value of ethanol = 15.9 very weak acid) and the conjugate base of weak acid is always a strong base. Secondly, the oxygen atom more Electronegative than Nitrogen atom can attract more electron cloud from alkyl group as compared to Nitrogen in ethylamine. Hence, oxygen in ethoxide attains greater electron cloud than the nitrogen in ethylamine. Therefore, it is more basic than ethylamine.
Answer:
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