As mentioned in the given question, the addition of 0.275 L of 1.62 M KCl is done in a solution that comprise Ag⁺ and Pb²⁺ ions so that all the ions get precipitated. Therefore, the moles of KCl present is,

Moles of KCl = 0.275 L × 1.62 M = 0.445 moles

Now the reaction will be,

Ag⁺ + Pb²⁺ + KCl ⇒ AgCl + PbCl₂ + 3K⁺

Now let us assume that the formation of x moles of AgCl and y moles of PbCl₂ is taking place.

Therefore, mass of AgCl will be x × molecular mass, which will be equal to x × 143.32 grams = 143.32 x grams

Now the mass of PbCl2 formed will be,

y × molecular mass = y × 278.1 grams = 278.1 y grams

Now the total precipitate will be,

62.37 grams = 143.32 x + 278.1 y -----------(i)

Now as AgCl and PbCl₂ requires 1:2 ratio of KCl, this shows that x moles of AgCl will require x moles of KCl and y mol of PbCl₂ will require 2*y moles of PbCl₂. Therefore,

x + 2y = total mass of KCl

x + 2y = 0.445 moles ------ (ii)

On solving equation (i) and (ii) we get,

x as 0.115 and y as 0.165

Now the mass of AgCl will be,

143.32 × 0.115 = 16.48 grams

The mass of PbCl₂ will be,

278.1 × 0.165 = 45.88 grams.

3 0

2 years ago

TIME REMAINING

otez555 [7]

Answer:

compound light microscope

6 0

1 year ago

purification of chromium can be achieved by electrorefining chromium from an impure chromium anode onto a pure chromium cathode

stiv31 [10]

The chromium in the electrolytic solution is present as cr³⁺ will take 6.19 hours will it take to plate 18.0 kg of chromium onto the cathode if the current passed through the cell is held constant at 45.0 A.

It is given that mass is 18 kg. Converting mass into grams

18 x (1000g / 1 kg)

= 18000 g

So, 18 kg = 18000 g

Now, calculate the number of moles

No. of moles = mass of Cr / molecular mass of Cr

No. of moles = 18000 / 52 g/mole

No. of moles = 346.15 mole

For , Cr³⁺, 3 moles of electrons are required

Hence,

3 x 346.15 mole

1038.45

As 96500 C of charge are present in 1 mole of electrons. As a result, the charge held by 1038.45 mole of electrons will be determined as follows.

= 1038.45mol x 96500 C / mole

= 10.02 x 10⁷ C

As, we know that relation between charge, current and time is as follows.

Q = I x T

Current is given as 45 A

Therefore, charge is calculated

T = Q / I

T = 100.21 x 10⁶ / 45

T = 2.227 x 10⁶

As there are 3600 seconds in one 1 hour. Converting 2.227 x 10⁶ into hours are

= 2.227 x 10⁶ / 3600 sec/h

= 6.19 hours

Thus, if the current flowing through the cell is maintained constant at 45 A, we may estimate that it will take 6.19 hours to plate 18 kg of chromium onto the cathode.

To know more about electrolytic solution visit :

brainly.com/question/9203208

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4 0

9 months ago