Given substances f2, kr, cl2 and hbr rank them with respect to the highest boiling point?
1 answer:
The Hbr has highest boiling point followed by Kr , and
.
The Hbr has highest boiling point due to presence of intermolecular H-bonding that is hydrogen bonding.
The electronegativity of bromine is greater than hydrogen atom. The electronegativity difference hydrogen atom and bromine atom is high. So, due to this a positive dipole is generated at hydrogen atom and partial negative charge, these partial charge is called dipole. In a HBr molecule one H-atom attracted by Br-atom of another atom by force of attraction and this partial force of attraction is called H-bonding.
Other all given molecules are arrange according to its molecular mass because boiling points is directly proportional to the molecular mass of molecule.
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The molar extinction coefficient is 15,200 .
The formula to be used to calculate molar extinction coefficient is -
A = ξcl, where A represents absorption, ξ refers molar extinction coefficient, c refers to concentration and l represents length.
The given values are in required units, hence, there is no need to convert them. Directly keeping the values in formula to find the value of molar extinction coefficient.
Rewriting the formula as per molar extinction coefficient -
ξ =
ξ =
Performing multiplication in denominator to find the value of molar extinction coefficient
ξ =
Performing division to find the value of molar extinction coefficient
ξ = 15,200
Hence, the molar extinction coefficient is 15,200 .
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