Answer: The bulk of liquids separate from the standard substance through crystallization, creating a crystalline block.
Freezing is almost often an exothermic mechanism which ensures that heat is emitted when liquid transforms into concrete.
The energy emitted after freezing, known as the fusion enthalpy, is a latent heat, which is precisely the same as the energy used to melt the same volume of solid.
C. quadruples the rate
<h3>Further explanation</h3>
Given
The rate law :
R=k[A]²
Required
The rate
Solution
There are several factors that influence reaction kinetics :
- 1. Concentration
- 2. Surface area
- 3. Temperature
- 4. Catalyst
- 5. Pressure
- 6. Stirring
The rate is proportional to the concentration.
If the concentration increased, the reaction rate will increase
The reaction is second-order overall(The exponent is 2)
The concentration of A is doubled, the reaction rate will increase :
r = k[A]² ⇒ r= k[2A]²⇒r=4k[A]²
<em>The reaction rate will quadruple.</em>
Y : CCP : 4 atoms
X : tetrahedral voids would be 1/3 × 8 = 8/3
so formula would be Y12X8 or Y3X2 !!
Answer :
(1) pH = 1.27
(2) pH = 13.35
(3) The given solution is not a buffer.
Explanation :
<u>(1) 53.1 mM HCl</u>
Concentration of HCl = 
As HCl is a strong acid. So, it dissociates completely to give hydrogen ion and chloride ion.
So, Concentration of hydrogen ion= 
pH : It is defined as the negative logarithm of hydrogen ion concentration.
![pH=-\log [H^+]](https://tex.z-dn.net/?f=pH%3D-%5Clog%20%5BH%5E%2B%5D)


<u>(2) 0.223 M KOH</u>
Concentration of KOH = 0.223 M
As KOH is a strong base. So, it dissociates completely to give hydroxide ion and potassium ion.
So, Concentration of hydroxide ion= 0.223 M
Now we have to calculate the pOH.
![pOH=-\log [OH^-]](https://tex.z-dn.net/?f=pOH%3D-%5Clog%20%5BOH%5E-%5D)


Now we have to calculate the pH.

<u>(3) 53.1 mM HCl + 0.223 M KOH</u>
Buffer : It is defined as a solution that maintain the pH of the solution by adding the small amount of acid or a base.
It is not a buffer because HCl is a strong acid and KOH is a strong base. Both dissociates completely.
As we know that the pH of strong acid and strong base solution is always 7.
So, the given solution is not a buffer.