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1 year ago

Given that E

1 answer:

5 0

The equilibrium constant of the reaction is 1.21 * 10^6 while the change in free energy is -34.7 kJ.

<h3>What is equilirium constant?</h3>

The equilibrium constant shows the extent of conversion of reactants to products.

Now we know from the Nernst equation that;

Ecell = E°cell - 0.0592/n logQ

E°cell = 0.52−0.16=0.36 V

Since Ecell = 0 V at equilibrium,

0 = 0.36 - 0.0592/1 log K

0.36 = 0.0592/1 log K

log K = 0.36/ 0.0592

K = antiog (0.36/ 0.0592)

K = 1.21 * 10^6

ΔG = -RT lnK

ΔG =-(8.314 * 298 * ln1.21 * 10^6)

ΔG =-34.7 kJ

Learn more about equilibrium constant:brainly.com/question/10038290

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3 years ago

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Para formar bronce, se mezclan 150g de cobre a 1100°C y 35g de estaño a 560°C. Determine la temperatura final del sistema.

jek_recluse [69]

Answer:

La temperatura final del sistema es 1029,346 °C.

Explanation:

Asumamos que el sistema conformado por el cobre y el estaño no tiene interacciones con sus alrededores. Por la Primera Ley de la Termodinámica, el cobre cede calor al estaño con tal de alcanzar el equilibrio térmico. El cobre se encuentra inicialmente en su punto de fusión, mientras que el estaño está por encima de ese punto, de modo que la transferencia de calor es esencialmente sensible:

$m_{Cu}\cdot c_{Cu}\cdot (T-T_{Cu}) = m_{Sn}\cdot c_{Sn}\cdot (T_{Sn}-T)$

$(m_{Cu}\cdot c_{Cu} + m_{Sn}\cdot c_{Sn})\cdot T = m_{Sn}\cdot c_{Sn}\cdot T_{Sn} + m_{Cu}\cdot c_{Cu}\cdot T_{Cu}$

$T = \frac{m_{Sn}\cdot c_{Sn}\cdot T_{Sn}+m_{Cu}\cdot c_{Cu}\cdot T_{Cu}}{m_{Cu}\cdot c_{Cu}+m_{Sn}\cdot c_{Sn}}$ (1)

Donde:

$m_{Sn}$ - Masa del estaño, en gramos.

$m_{Cu}$ - Masa del cobre, en gramos.

$c_{Sn}$ - Calor específico del estaño, en calorías por gramo-grados Celsius.

$c_{Cu}$ - Calor específico del cobre, en calorías por gramo-grados Celsius.

$T_{Sn}$ - Temperatura inicial del estaño, en grados Celsius.

$T_{Cu}$ - Temperatura inicial del cobre, en grados Celsius.

Si sabemos que $m_{Cu} = 150\,g$ , $m_{Sn} = 35\,g$ , $c_{Cu} = 0,093\,\frac{cal}{g\cdot ^{\circ}C}$ , $c_{Sn} = 0,060\,\frac{cal}{g\cdot ^{\circ}C}$ , $T_{Sn} = 560\,^{\circ}C$ y $T_{Cu} = 1100\,^{\circ}C$ , entonces la temperatura final del sistema es:

$T = \frac{(35\,g)\cdot \left(0,060\,\frac{cal}{g\cdot ^{\circ}C} \right)\cdot (560\,^{\circ}C)+(150\,g)\cdot \left(0,093\,\frac{cal}{g\cdot ^{\circ}C} \right)\cdot (1100\,^{\circ}C)}{(35\,g)\cdot \left(0,060\,\frac{cal}{g\cdot ^{\circ}C} \right)+(150\,g)\cdot \left(0,093\,\frac{cal}{g\cdot ^{\circ}C} \right)}$

$T = 1029,346\,^{\circ}C$

La temperatura final del sistema es 1029,346 °C.

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