Hi, here is a basic summary of what we did in a lab; there were 3 reactions: The procedure: Reaction 1: Solid sodium hydroxide dissolves in water to form an aqueous solution of ions. NaOH(s)-> Na+(aq) + OH-(aq) ΔH1=-34.121kJ Reaction 2: Solid sodium hydroxide reacts with an aqueous solution of HCl to form water and an aqueous solution of sodium chloride. NaOH(s) + H+(aq) + Cl-(aq) -> H2O + Na+(aq) + Cl-(aq) ΔH2=-83.602kJ Reaction 3: An aqueous solution of sodium hydroxide reacts with an aqueous solution of HCl to form water an an aqueous solution of sodium chloride. H+(aq) + OH-(aq) + Na+(aq) + Cl-(aq) -> H2O + Na+(aq) + Cl-(aq) ΔH3= -50.2kJ The ΔH values were calculated by dividing the heat gained by the number of moles (each reaction had 0.05moles of NaOH) The problem: Net ionic equations for reaction 2 & 3: 2: NaOH(s) + H+(aq) -> H2O + Na+(aq) 3: H+(aq) + OH-(aq) -> H2O i) In reaction 1, ΔH1 represents the heat evolved as solid NaOH dissolves. Look at the net ionic equations for reactions 2 and 3 and make similar statements as to what ΔH2 and ΔH3 represent. ii) Compare ΔH2 with (ΔH1 + ΔH3). Explain in sentences the similarity between these two values by using your answer to #5 above. Attempt at answering: i) Firstly, ΔH2 represents the heat evolved as the hydrogen ion displaces the sodium ion, creating a single displacement reaction. ΔH3 represents the heat evolved as the hydrogen and hydroxide ion form water via a neutralization reaction. ii) ΔH2 is equal to (or supposed to be, this is a source of error while calculating) (ΔH1 + ΔH3). The similarity between these two values is that .. (this is where I get confused!)
Source https://www.physicsforums.com/threads/calorimetry-help-chemistry.399653/
Look at the periodic table to find the charge on atoms.
Magnesium is +2 and Nitrogen is -3. Since there are two nitrogen charge 2*-3 = -6 there needs to be 3 Mg then (3*2+ = 6+) to pair with the two nitrogen.
3 Mg(+2) + 2 N(-3) = Mg3N2
Answer:
The pH value of the mixture will be 7.00
Explanation:
Mono and disodium hydrogen phosphate mixture act as a buffer to maintain pH value around 7. Henderson–Hasselbalch equation is used to determine the pH value of a buffer mixture, which is mathematically expressed as,
![pH=pK_{a} + log(\frac{[Base]}{[Acid]})](https://tex.z-dn.net/?f=pH%3DpK_%7Ba%7D%20%2B%20log%28%5Cfrac%7B%5BBase%5D%7D%7B%5BAcid%5D%7D%29)
According to the given conditions, the equation will become as follow
![pH=pK_{a} + log(\frac{[Na_{2}HPO_{4} ]}{[NaH_{2}PO_{4}]})](https://tex.z-dn.net/?f=pH%3DpK_%7Ba%7D%20%2B%20log%28%5Cfrac%7B%5BNa_%7B2%7DHPO_%7B4%7D%20%5D%7D%7B%5BNaH_%7B2%7DPO_%7B4%7D%5D%7D%29)
The base and acid are assigned by observing the pKa values of both the compounds; smaller value means more acidic. NaH₂PO₄ has a pKa value of 6.86, while Na₂HPO₄ has a pKa value of 12.32 (not given, but it's a constant). Another more easy way is to the count the acidic hydrogen in the molecular formula; the compound with more acidic hydrogens will be assigned acidic and vice versa.
Placing all the given data we obtain,


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