<span>The student should
follow following steps to make 1 L of </span>2.0 M CaCl₂.<span>
<span>
1. First he should
calculate the number of moles of 2.0 M CaCl</span></span>₂ in 1 L solution.<span>
</span>Molarity of the solution = 2.0 M<span>
Volume of solution which should be prepared = 1 L
Molarity =
number of moles / volume of the solution
Hence, number of moles in 1 L = 2 mol
2. Find
out the mass of dry CaCl</span>₂ in 2 moles.<span>
moles =
mass / molar mass
Moles of CaCl₂ =
2 mol</span><span>
Molar mass of CaCl₂ = </span><span>110.98 g/mol
Hence, mass of CaCl</span>₂ = 2 mol x <span>110.98 g/mol
= 221.96
g
3. Weigh the mass
accurately
4. Then take a cleaned and dry1 L volumetric flask and place a funnel top of it. Then carefully add the salt into the volumetric flask and
finally wash the funnel and watch glass
with de-ionized water. That water also should be added into the volumetric
flask.
5. Then add some
de-ionized water into
the volumetric flask and swirl well until all salt are
dissolved.
<span>6. Then top up to
mark of the volumetric flask carefully.
</span></span>
7. As the final step prepared solution should be labelled.
Boiling point elevation is given as:
ΔTb=iKbm
Where,
ΔTb=elevation in the boiling point
that is given by expression:
ΔTb=Tb (solution) - Tb (pure solvent)
Here Tb (pure solvent)=118.1 °C
i for CaCO3= 2
Kb=2.93 °C/m
m=Molality of CaCO₃:
Molality of CaCO₃=Number of moles of CaCO₃/ Mass of solvent (Kg)
=(Given Mass of CaCO3/Molar mass of CaCO₃)/ Mass of solvent (Kg)
=(100.0÷100 g/mol)/0.4
= 2.5 m
So now putting value of m, i and Kb in the boiling point elevation equation we get:
ΔTb=iKbm
=2×2.93×2.5
=14.65 °C
boiling point of a solution can be calculated:
ΔTb=Tb (solution) - Tb (pure solvent)
14.65=Tb (solution)-118.1
Tb (solution)=118.1+14.65
=132.75
Violet, indigo, blue, green, yellow, orange, red
Answer:
Explanation:
1. Calculate the work
w = - pΔV = -4.3 atm × (43 L - 20 L) = -4.3 × 23 L·atm = -98.9 L·atm
2. Convert litre-atmospheres to joules
The negative sign indicates that the work was done against the surroundings.
