ΔG⁰ = ΔH⁰ - TΔS
ΔH⁰ = Hf,(CH₃OH) - Hf,(CO) = -238.7 + 110.5 = -128.2 kJ/mol
ΔS = S(CH₃OH) - S(CO) - 2S(H₂) = 126.8 - 197.7 - 2 x 130.6 = -332.1 J/mol.K
So
ΔG⁰ = - 128200 + 332.1 T
For the reaction to be spontaneous:
ΔG⁰ < 0
So: -128200 + 332.1 T < 0
332.1 T < 128200
T < 386.028 K
Answer:
draw the carbon chain is containing 6 carbon then attach the aldehyde group with edge carbon in chain then put the put double bond at 3 no. carbon
Let initially there are 10 molecules of O2 and 3 molecules of C3H8 present
The reaction will be
C3H8(g) + 5O2(g) ----> 3CO2(g) + 4H2O
so here oxygen molecules are limiting as for 3 molecules of C3H8 we need 15 molecules of O2
now the given 10 molecules of O2 will react with only 2 molecules of C3H8 and they will form six molecules of CO2 and 8 molecules of H2O
Hence answer is
molecules of CO2 formed = 6
Molecules of H2O formed = 8
molecules of C3H8 left = 1
molecules of O2 left = 0
When HCl is added to a saturated solution of PbCl2, the solubility of PbCl2 would decrease so precipitation would occur. The decrease in the solubility is due to the common ion effect or the presence of Cl- ions in both compounds.
