I believe your answer is 23.
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The sun's rays hit the Earth at a extreme angle, which causes the days to become shorter, so yes, the sun's rays do hit the Earth at a extreme angle.
#b
According to Le C ha.te llors principle of we increase concentration of reactants or products equilibrium shifts.
#c
- Rate of reaction also increases
#e
Stated in b
1.35atm(760mmHg/1atm)=1026mmHg