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For this question, I think it is the other way around. It is true that chloroacetic acid is stronger in strength than acetic acid. Acid strength is measured as the equilibrium constant of the reaction <span>HA -----> H+ + A-
</span><span> In acetic acid, the anion produced by dissociation is CH3-COO-; in chloroacetic acid it is CH2Cl-COO-. Comparing the two, in the first one the negative charge is taken up mostly by the two oxygen atoms. In the second there is also an electronegative chlorine atom nearby to draw more charge towards itself. Therefore, the charge is less concentrated in the chloroacetate ion than it is in the acetate ion, and, accordingly, chloroacetic acid is stronger than acetic acid. </span>
High pressures are necessary to create such reaction so that the particles will be able to overcome electrostatic repulsion. The particles that make up a particular atom are covered by shells of energy that react to different impulses like pressure. When particles are exposed to extreme environmental pressure it has the tendency to split its particles and undergo nuclear fusion successfully.
Answer:
The correct answer is:
<em>(1) It is important that the sample is dissolved in just enough hot solvent. </em>
Explanation:
The process of recrystallization is important to eliminate the impurities and to obtain better crystals of the solid. The solvent used to perform the recrystallization must have a high dissolution power of the substance to be recrystallized and a low dissolution power of the impurities. This is in order to eliminate most impurities. Furthermore, <em>It is important that the sample is dissolved in just enough hot solvent </em>because this should be easy to remove after the recrystallization and the crystal should form easily when the solution cools. Also, it is better to add the hot solvent to solubilize the crystals and keep the impurities insoluble, instead of adding the cold solvent and heating the solution. Additionally, the process of cooling the solution must be done slowly to obtain large and fewer crystals. A fast ice-cooling will form smaller crystals.
Answer:
1.12g/mol
Explanation:
The freezing point depression of a solvent for the addition of a solute follows the equation:
ΔT = Kf*m*i
<em>Where ΔT is change in temperature (Benzonitrile freezing point: -12.82°C; Freezing point solution: 13.4°C)</em>
<em>ΔT = 13.4°C - (-12.82) = 26.22°C</em>
<em>m is molality of the solution</em>
<em>Kf is freezing point depression constant of benzonitrile (5.35°Ckgmol⁻¹)</em>
<em>And i is Van't Hoff factor (1 for all solutes in benzonitrile)</em>
Replacing:
26.22°C = 5.35°Ckgmol⁻¹*m*1
4.90mol/kg = molality of the compound X
As the mass of the solvent is 100g = 0.100kg:
4.9mol/kg * 0.100kg = 0.490moles
There are 0.490 moles of X in 551mg = 0.551g, the molar mass (Ratio of grams and moles) is:
0.551g / 0.490mol
= 1.12g/mol
<em>This result has no sense but is the result by using the freezing point of the solution = 13.4°C. Has more sense a value of -13.4°C.</em>
