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natali 33 [55]
1 year ago
10

The diagram shows the potential energy changes for a reaction pathway.

Chemistry
1 answer:
Nitella [24]1 year ago
3 0

1) To find the change in enthalpy, determine the difference between the potential energy of the products and the potential energy of the reactants. (on this diagram, C-A) To find the activation energy, find the difference between the potential energy of the reactants and the "peak" of the curve (on this diagram, B-A). For this diagram, both the enthalpy and activation energy are positive.

2) If the reaction was exothermic, enthalpy would be negative, and the potential energy of the reactants would be greater than the potential energy of the products.

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Determine the mole fractions and partial pressures of CO2, CH4, and He in a sample of gas that contains 1.20 moles of CO2, 1.79
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Moles of He = 3.71 mole

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\text{Mole fraction of }CH_4=\frac{\text{Moles of }CH_4}{\text{Moles of }CH_4+\text{Moles of }CO_2+\text{Moles of }He}

\text{Mole fraction of }CH_4=\frac{1.79}{1.79+1.20+3.71}=0.267

and,

\text{Mole fraction of }CO_2=\frac{\text{Moles of }CO_2}{\text{Moles of }CH_4+\text{Moles of }CO_2+\text{Moles of }He}

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and,

\text{Mole fraction of }He=\frac{\text{Moles of }He}{\text{Moles of }CH_4+\text{Moles of }CO_2+\text{Moles of }He}

\text{Mole fraction of }He=\frac{3.71}{1.79+1.20+3.71}=0.554

Thus, the mole fraction of CH_4,CO_2 and He gases are, 0.267, 0.179 and 0.554 respectively.

Now we have to calculate the partial pressure of CH_4,CO_2 and He gases.

According to the Raoult's law,

p_i=X_i\times p_T

where,

p_i = partial pressure of gas

p_T = total pressure of gas  = 5.78 atm

X_i = mole fraction of gas

p_{CH_4}=X_{CH_4}\times p_T

p_{CH_4}=0.267\times 5.78atm=1.54atm

and,

p_{CO_2}=X_{CO_2}\times p_T

p_{CO_2}=0.179\times 5.78atm=1.03atm

and,

p_{He}=X_{He}\times p_T

p_{He}=0.554\times 5.78atm=3.20atm

Thus, the partial pressure of CH_4,CO_2 and He gases are, 1.54, 1.03 and 3.20 atm respectively.

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