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slamgirl [31]
3 years ago
11

Equilibrium describes the balance that results from a forward and reverse reaction proceeding at equal rates. Since reaction rat

es depend on concentration, temperature, and pressure, any changes in these conditions may alter the forward and reverse rates unequally and disrupt the equilibrium.
Le Chatelier's principle states that after a change in conditions displaces a reaction from equilibrium

a) the reaction will undergo a temperature change in order to offset the disturbance.

b) the reaction proceeds to a new equilibrium in the direction that offsets the change.

c) the disturbance will always cause the forward reaction to be slower than the reverse reaction.

d) the change in conditions must be reversed in order to regain equilibrium.
Chemistry
1 answer:
Delvig [45]3 years ago
5 0

Answer:

b) the reaction proceeds to a new equilibrium in the direction that offsets the change.

Explanation:

According to Le Chatelier's principle, when a system experiences a constraint such as a change in pressure, temperature or concentration, the system will readjust itself in order to annul the constraint.

This simply means that when temperature, concentration or pressure is changed, a new equilibrium position is reached in order to offset the changes in the system.

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Assume that the density and heat of combustion of E85 can be obtained by using 85 % of the values for ethanol and 15 % of the va
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Answer:

87.4 J

Explanation:

The density of the gasoline is 0.70 g/mL, and the density of the ethanol is 0.79 g/mL. The heat combustions (the heat released in a combustion reaction) are 5,400 kJ/mol for gasoline, and 1,370 kJ/mol for ethanol.

For 3.5 L of E85, the volumes of gasoline and ethanol are:

Vgasoline = 0.15 * 3.5 = 0.525 L = 5.25x10⁻⁴ mL

Vethanol= 0.85 * 3.5 = 2.975 L = 2.975x10⁻³ mL

The mass of gasoline and ethanol presented in that sample of E85 is the volume multiplied by the density:

mgasoline = 5.25x10⁻⁴ * 0.70 = 3.675x10⁻⁴ g

methanol = 2.975x10⁻³ * 0.79 = 2.35025x10⁻³ g

The number of moles for each substance is it mass divided by its molar mass. The molar masses are 114 g/mol for gasoline, and 46 g/mol for ethanol:

ngasoline = 3.675x10⁻⁴/114 = 3.224x10⁻⁶ mol

nethanol = 2.35025x10⁻³ /46 = 5.109x10⁻⁵ mol

The energy released is the heat combustion multiplied by the number of moles, so:

Egasoline = 5,400 * 3.224x10⁻⁶ = 0.0174 kJ = 17.4 J

Eethanol = 1,370 * 5.109x10⁻⁵ = 0.07 kJ = 70 J

So, the energy released by the E85 is the sum of the energy released by ethanol and gasoline:

The energy released by E85 = 87.4 J

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