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Anna11 [10]
3 years ago
8

Current of 250. a flows for 24.0 hours at an anode where the reaction occurring is as follows: mn2+(aq) + 2h2o(l) → mno2(s) + 4h

+(aq) + 2e–what mass of mno2 is deposited at this anode?
Chemistry
2 answers:
Tju [1.3M]3 years ago
7 0
From Faraday's 1st law of electrolysis,
Total electricity passed into system = Q = IT = 250 X 24 X 60 X 60
                                                                       = 2.16 X 10^7 C

We know that, 96500 C = 1 F
∴ 2.16 X 10^7 C =  <span>223.8 F
</span>
Now, number of moles of<span> MnO2  deposited = 223.8/2=111.9 
</span>
Finally, 1 mole of MnO2 ≡ 86.94 g
∴ 111.9 mole of MnO2 ≡  111.9 X 86.94 = 9728 g

Thus, <span>mass of MnO2 that will be deposited at anode = 9728 g</span>
Colt1911 [192]3 years ago
7 0

Answer:

The mass of mno2 is deposited at this anode is 9.732x10³ g

Explanation:

please look at the solution in the attached Word file

Download docx
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Answer:

\large \boxed{34.2\, ^{\circ}\text{C}}

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m_{1} =\text{125 g; }T_{i} = 93.2 ^{\circ}\text{C; }\\C_{1} = 0.900 \text{ J$^{\circ}$C$^{-1}$g$^{-1}$}

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\begin{array}{rcl}\text{Heat lost by metal + heat gained by water} & = & 0\\q_{1} + q_{2} & = & 0\\m_{1}C_{1}\Delta T_{1} + m_{2}C_{2}\Delta T_{2} & = & 0\\\text{125 g}\times 0.900 \text{ J$^{\circ}$C$^{-1}$g$^{-1}$} \times\Delta T_{1} + \text{100 g} \times 4.184 \text{ J$^{\circ}$C$^{-1}$g$^{-1}$}\Delta \times T_{2} & = & 0\\112.5\Delta T_{1} + 418.4\Delta T_{2} & = & 0\\112.5\Delta T_{1} & = & -418.4\Delta T_{2}\\\Delta T_{1} & = & -3.719\Delta T_{2}\\\end{array}

\Delta T_{1} = T_{\text{f}} - 93.2 ^{\circ}\text{C}\\\Delta T_{2} = T_{\text{f}} - 18.3 ^{\circ}\text{C}

\begin{array}{rcl}\Delta T_{1} & = & -3.719\Delta T_{2}\\T_{\text{f}} - 93.2 ^{\circ}\text{C} & = & -3.719 (T_{\text{f}} - 18.3 ^{\circ}\text{C})\\T_{\text{f}} - 93.2 ^{\circ}\text{C} & = & -3.719T_{\text{f}} + 68.06 ^{\circ}\text{C}\\4.719T_{\text{f}} & = & 161.3 ^{\circ}\text{C}\\T_{\text{f}} & = & \mathbf{34.2 ^{\circ}}\textbf{C}\\\end{array}\\\text{The final temperature of the block and the water is $\large \boxed{\mathbf{34.2\, ^{\circ}}\textbf{C}}$}

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