Answer:
D because excited electrons fall back.....
The average kinetic energy of 1 mole of a gas at -32 degrees Celsius is:
3.80 x 103 J
The relationship between volume and temperature of a gas, when pressure and moles of a gas are held constant, is: V*T = k.
FALSE
The relationship between moles and volume, when pressure and temperature of a gas are held constant, is: V/n = k. We could say then, that:
If the moles of gas are tripled, the volume must also triple.
If the temperature and volume of a gas are held constant, an increase in pressure would most likely be caused by an increase in the number of moles of gas.
TRUE
If the vapor pressure of a liquid is less than the atmospheric pressure, the liquid will not boil.
TRUE
35 - AB
36 - BD
33 - true
34 - False
20 - 6
21 - orthohombic
Answer:Acid catalyst is needed to increase the electrophilicity of Carbonyl group of Carboxylic acid as alcohol is a weak nucleophile.
Alternatively esters can be synthesised by converting carboxylic acid into acyl chloride using thionyl chloride(SOCl_{2} and then further treating acyl chloride with alcohol.
Carboxylic acid and esters can be easily distinguished on the basis of IR as carboxylic acid would contain a broad intense peak in 2500-3200cm_{-1} corresponding to OH stretching frequency whereas esters would not contain any such broad intense peak.
Alcohol and esters can also be distinguished using IR as alcohols would contain a broad intense peak at around 3200-3600cm_{-1}
Explanation: For the synthesis of esters using alcohol and carboxylic acid we need to add a little amount of acid in the reaction . The acid used here increases the electrophilicity of carbonyl carbon and hence makes it easier for a weaker nucleophile like alcohol to attack the carbonyl carbon of acid.
The oxygen of the carbonyl group is protonated using the acidic proton which leads to the generation of positive charge on the oxygen. The positive charge generated is delocalised over the whole acid molecule and hence the electrophilicity of carbonyl group is increased. Kindly refer attachment for the structures.
If we simply mix the acid and alcohol then no appreciable reaction would take place between them and ester formation would not take place because the carboxylic acid in that case is not a good electrophile whereas alcohol is also not a very strong nucleophile which can attack the carbonyl group.
Alternatively we can use thionyl chloride or any other reagent which can convert the carboxylic acid into acyl chloride. Acyl chloride is very elctrophilic and alcohol can very easily attack the acyl chloride and esters could be synthesized.
The carboxylic acid and ester can very easily be distinguished on the basis of broad intense OH stretching frequency peak at around 2500-3200cm_{-1} . The broad intense OH stretching frequency peak is present in carboxylic acids as they contain OH groups and absent in case of esters .
Likewise esters and alcohols can also be distinguished on the basis IR spectra as alcohols will have broad intense spectra at around 3200-3600cm_{-1}corresponding to OH stretching frequency whereas esters will not have any such peak. Rather esters would be having a Carbonyl stretching frequency at around 1720-1760
Answer:
7.28 mol Na2SO4
Explanation:
Since it is already in moles, all we have to do is use a molar ratio
A molar ratio is the proportions of reactants and products using the balanced equation. When writing a mole ratio, the given information must cross out with the right thing.
7.28 mol H2SO4 * 1 mol Na2SO4/1 H2SO4 = 7.28 mol Na2SO4
*notice how the H2SO4 crosses out