Explanation:
Entropy means the amount of randomness present within the molecules of the body of a substance.
Relation between entropy and microstate is as follows.
S = 
where, S = entropy
= Boltzmann constant
= number of microstates
This equation only holds good when the system is neither losing or gaining energy. And, in the given situation we assume that the system is neither gaining or losing energy.
Also, let us assume that
= 1, and
= 0.833
Therefore, change in entropy will be calculated as follows.

= 
= 
= 
or, = 
Thus, we can conclude that the entropy change for a particle in the given system is
J/K particle.
It would be 6 because of the elements
D! It’s a pure substance and a compound
The HCl added = 1.25 moles
and the moles of Na2HPO4 = 1 mole
Now when acid is added in the given solution of Na2HPO4
One mole of H+ will react with one mole of Na2HPO4 to given one mole of NaH2PO4
Na2HPO4 + H+ ---> NaH2PO4
Now this one mole formed NaH2PO4 will further react with 0.25 moles of H+ left to form 0.25 moles of H3PO4 and 0.75 moles of NaH2PO4 will remain in the solution
So this will result into formation of a buffer of phosphoric acid and NaH2PO4
NaH2PO4 + H+ ---> H3PO4
pKa of H3PO4 = 2.1
so pH = pKa + log [salt] / [acid] = 2.1 + log [0.75 / 0.25] = 2.58
so the pH will be in between 2.1 to 7.2