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irina1246 [14]
2 years ago
14

Calculate the osmotic pressure of 20 m solution of LiCl at 25C

Chemistry
1 answer:
Soloha48 [4]2 years ago
5 0

Answer:

979 atm

Explanation:

To calculate the osmotic pressure, you need to use the following equation:

π = <em>i </em>MRT

In this equation,

-----> π = osmotic pressure (atm)

-----><em> i</em> = van't Hoff's factor (number of dissolved ions)

-----> M = Molarity (M)

-----> R = Ideal Gas constant (0.08206 L*atm/mol*K)

-----> T = temperature (K)

When LiCl dissolves, it dissociates into two ions (Li⁺ and Cl⁻). Therefore, van't Hoff's factor is 2. Before plugging the given values into the equation, you need to convert Celsius to Kelvin.

<em>i </em>= 2                             R = 0.08206 L*atm/mol*K

M = 20 M                    T = 25°C + 273.15 = 298.15 K

π = <em>i </em>MRT

π = (2)(20 M)(0.08206 L*atm/mol*K)(298.15 K)

π = 979 atm

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3Cu + 8HNO = 3Cu(NO3)2 +2NO + 4H2O
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Taking into account the reaction stoichiometry, 5.2634 grams of Cu(NO₃)₂ are formed when 4.69 grams of HNO₃, assuming an excess of solid copper is present.

<h3>Reaction stoichiometry</h3>

In first place, the balanced reaction is:

3 Cu+ 8 HNO₃ → 3 Cu(NO₃)₂ + 2 NO + 4 H₂O

By reaction stoichiometry (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:

  • Cu: 3 moles
  • HNO₃: 8 moles
  • Cu(NO₃)₂: 3 mole
  • NO: 2 moles
  • H₂O: 4 moles

The molar mass of the compounds is:

  • Cu: 63.55 g/mole
  • HNO₃: 63 g/mole
  • Cu(NO₃)₂: 187.55 g/mole
  • NO: 30 g/mole
  • H₂O: 18 g/mole

Then, by reaction stoichiometry, the following mass quantities of each compound participate in the reaction:

  • Cu: 3 moles ×63.55 g/mole= 190.65 grams
  • HNO₃: 8 moles ×63 g/mole= 504 grams
  • Cu(NO₃)₂: 3 moles ×187.55 g/mole= 562.65 grams
  • NO: 2 moles ×30 g/mole= 60 grams
  • H₂O: 4 moles ×18 g/mole= 72 grams

<h3>Mass of Cu(NO₃)₂ produced</h3>

The following rule of three can be applied: if by reaction stoichiometry 504 grams of HNO₃ form 562.65 grams of Cu(NO₃)₂, 4.69 grams of HNO₃ form how much mass of Cu(NO₃)₂?

mass of Cu(NO_{3} )_{2} =\frac{4.69 grams of HNO_{3}  x562.65 grams of Cu(NO_{3} )_{2} }{504 grams of HNO_{3} }

<u><em>mass of Cu(NO₃)₂=  5.2634 grams</em></u>

Then, 5.2634 grams of Cu(NO₃)₂ are formed when 4.69 grams of HNO₃, assuming an excess of solid copper is present.

Learn more about the reaction stoichiometry:

brainly.com/question/24741074

brainly.com/question/24653699

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