Answer:
56°
Explanation:
First calculate 
The interplanar spacing can be calculated from:
The diffraction angle is determined from:
Solve for 
The diffraction angle is:
Yes. Heating up the solvent gives the molecules more kinetic energy. The more rapid motion means that the solvent molecules collide with the solute with greater frequency and the collisions occur with more force. Both factors increase the rate at which the solute dissolves.
Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.
Answer : The molarity and molality of the solution is, 18.29 mole/L and 499.59 mole/Kg respectively.
Solution : Given,
Density of solution = 
Molar mass of sulfuric acid (solute) = 98.079 g/mole
98.0 % sulfuric acid by mass means that 98.0 gram of sulfuric acid is present in 100 g of solution.
Mass of sulfuric acid (solute) = 98.0 g
Mass of solution = 100 g
Mass of solvent = Mass of solution - Mass of solute = 100 - 98.0 = 2 g
First we have to calculate the volume of solution.
Now we have to calculate the molarity of solution.
Now we have to calculate the molality of the solution.
Therefore, the molarity and molality of the solution is, 18.29 mole/L and 499.59 mole/Kg respectively.
Answer:
Explanation:
The Ce metal has electronic configuration as follows
[Xe] 4f¹5d¹6s²
After losing 4 electrons , it gains noble gas configuration ,. So Ce ⁺⁴ is stable.
Eu has electronic configuration as follows
[ Xe ] 4 f ⁷6s²
[ Xe ] 4 f ⁷
Its outermost orbit contains 2 electrons so Eu²⁺ is stable. Its +3 oxidation state is also stable.
Ce⁺²
