Answer: a) 
b) 1 mole of 
is produced.
Explanation:
According to the law of conservation of mass, mass can neither be created nor be destroyed. Thus the mass of products has to be equal to the mass of reactants. The number of atoms of each element has to be same on reactant and product side. Thus chemical equations are balanced.
The skeletal equation is:
The balanced equation will be:
Thus the coefficients are 2, 3 , 10 , 4 , 3 , 2 and 5.
b) Oxidation: 
Reduction: 
Net reaction: 
When 1 mole of 
is produced, 1 mole of is produced.
Constant Volume Calorimetry, also know as bomb calorimetry, is used to measure the heat of a reaction while holding volume constant and resisting large amounts of pressure. Although these two aspects of bomb calorimetry make for accurate results, they also contribute to the difficulty of bomb calorimetry. In this module, the basic assembly of a bomb calorimeter will be addressed, as well as how bomb calorimetry relates to the heat of reaction and heat capacity and the calculations involved in regards to these two topics.
Introduction
Calorimetry is used to measure quantities of heat, and can be used to determine the heat of a reaction through experiments. Usually a coffee-cup calorimeter is used since it is simpler than a bomb calorimeter, but to measure the heat evolved in a combustion reaction, constant volume or bomb calorimetry is ideal. A constant volume calorimeter is also more accurate than a coffee-cup calorimeter, but it is more difficult to use since it requires a well-built reaction container that is able to withstand large amounts of pressure changes that happen in many chemical reactions.
Most serious calorimetry carried out in research laboratories involves the determination of heats of combustion ΔHcombustion" role="presentation" style="display: inline-table; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">ΔHcombustionΔHcombustion, since these are essential to the determination of standard enthalpies of formation of the thousands of new compounds that are prepared and characterized each month. In a constant volume calorimeter, the system is sealed or isolated from its surroundings, and this accounts for why its volume is fixed and there is no volume-pressure work done. A bomb calorimeter structure consists of the following:
Steel bomb which contains the reactantsWater bath in which the bomb is submergedThermometerA motorized stirrerWire for ignition
is usually called a “bomb”, and the technique is known as bomb calorimetry
Another consequence of the constant-volume condition is that the heat released corresponds to qv , and thus to the internal energy change ΔUrather than to ΔH. The enthalpy change is calculated according to the formula
(1.1)ΔH=qv+ΔngRT" role="presentation" style="display: inline-table; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: center; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; width: 10000em !important; position: relative;">ΔH=qv+ΔngRT(1.1)(1.1)ΔH=qv+ΔngRT
Δng" role="presentation" style="display: inline-table; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">ΔngΔng is the change in the number of moles of gases in the reaction.
Your reaction
.. Fe + O2 ---> FexOy
for this reaction..
.. the Fe on the left is in the 0 oxidation state
.. the Fe on the right is in the +(2y/x) oxidation state
.. the O on the left is in the 0 oxidation state
.. the O on the right is in the -2 oxidation state
meaning
.. the O is reduced... . . (it's reduced in oxidation state)
.. the Fe is oxidized.. . .(oxidation state increased)
this is a REDOX reaction
*********
AND.. it's also a synthesis reaction.. (aka combination reaction)
Answer:
a) 
b) entropy of the sistem equal to a), entropy of the universe grater than a).
Explanation:
a) The change of entropy for a reversible process:
The energy balance:
![\delta U=[tex]\delta Q- \delta W](https://tex.z-dn.net/?f=%5Cdelta%20U%3D%5Btex%5D%5Cdelta%20Q-%20%5Cdelta%20W)
If the process is isothermical the U doesn't change:
![0=[tex]\delta Q- \delta W](https://tex.z-dn.net/?f=0%3D%5Btex%5D%5Cdelta%20Q-%20%5Cdelta%20W)
The work:
If it is an ideal gas:
Solving:
Replacing:
Given that it's a compression: V2<V1 and ln(V2/V1)<0. So:
b) The entropy change of the sistem will be equal to the calculated in a), but the change of entropy of the universe will be 0 in a) (reversible process) and in b) has to be positive given that it is an irreversible process.
Answer:
K = 137.55 atm/M.
Explanation:
- The relationship between gas pressure and the concentration of dissolved gas is given by Henry’s law:
<em>P = (K)(C)</em>
where P is the partial pressure of the gaseous solute above the solution (P = 1.0 atm).
k is a constant (Henry’s constant).
C is the concentration of the dissolved gas (C = 7.27 x 10⁻³ M).
∴ K = P/C = (1.0 atm)/(7.27 x 10⁻³ M) = 137.55 atm/M.
