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Nina [5.8K]
2 years ago
13

Consider the reaction in the lead-acid cell pb(s) pbo2(s) 2 h2so4(aq) 2 pbso4(aq) 2 h2o(l) for which e°cell = 2. 04 v at 298 k.

δg° for this reaction is:________
Chemistry
1 answer:
aleksley [76]2 years ago
8 0

δg° for the reaction having e° cell = 2.04v. is 393.658kJ.

The lead (Pb) in the lead storage battery act as an anode

<h3>What is Voltaic Cell?</h3>

A voltaic cell or galvanic cell is an electrochemical cell that uses chemical reactions to produce electrical energy.

<h3>Parts of voltaic cell</h3>

Anode where oxidation occurs Cathode where reduction occurs.

Therefore, Pb acts as anode and PbO2 act as a cathode.

Given,

E° cell = 2.04v

Faraday constant= 96485 C/mol

Moles of electron transferred n= 2

∆G = -nFE°

= -2 × 96485 × 2.04

= 393.658kJ

Thus we concluded that the δg° for the reaction having e° cell = 2.04v. is 393.658kJ.

learn more about voltaic cell :

brainly.com/question/1370699

#SPJ4

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A beaker with 1.60×102 mL of an acetic acid buffer with a pH of 5.000 is sitting on a benchtop. The total molarity of acid and c
stich3 [128]

Answer:

The pH will change 0.16 ( from 5.00 to 4.84)

Explanation:

Step 1: Data given

volume of acetic acid buffer = 160 mL

The total molarity of acid and conjugate base in this buffer is 0.100 M

A student adds 7.10 mL of a 0.460 M HCl solution to the beaker.

The pKa of acetic acid is 4.740

pH = 5.00

Step 2: Calculate concentration of acid

Consider x = concentration acid

Consider y = concentration conjugate base

x + y = 0.100

5.00 = 4.740 + log y/x

5.00 - 4.740 = log y/x

0.26 = log y/x

10^0.26 =1.82 = y/x

1.82 x = y

Since x+y = 0.100

x + 1.82 x = 0.100

2.82 x = 0.100

x =0.0355 M = concentration acid

Step 3: Calculate concentration of conjugate base

y = 0.100 - x

0.100 - 0.0355 =0.0645 M= concentration conjugate base

Step 4: Calculate moles of acid

Moles = volume * molarity

moles acid = 0.160 L * 0.0355 M= 0.00568  moles

Step 5: Calculate moles of conjugate base

moles conjugate base = 0.0645 M * 0.160 L=0.01032 moles

Step 6: Calculate moles HCl

moles HCl = 7.10 * 10^-3 L * 0.460 M=0.003266 moles

Step 7: Calculate new moles

A- + H+ = HA

moles conjugate base = 0.01032 - 0.003266 =0.007054  moles

moles acid = 0.00568 + 0.003266=0.008946 moles

Step 8: Calculate the total volume

total volume = 160 + 7.10 = 167.1 mL = 0.1671 L

Step 9: Calculate the concentration of the acid

concentration acid = 0.008946/ 0.1671 =0.0535 M

Step 10: Calculate the concentration of conjugate base

concentration conjugate base = 0.007054/ 0.1671 =0.0422 M

Step 11: Calculate the pH

pH = 4.740 + log 0.0535/ 0.0422=4.84

change pH = 5.00 - 4.84=0.16

The pH will change 0.16

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