Explanation:
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TMS stands for Tetramethylsilane
Formula : Si(CH₃)₄
It is used as internal standard for chemical shift
In TMS all the four methyl groups are similar thus all the 12 hydrogen are chemically equivalent. They will show proton NMR at same level and which will appear as a singlet.
We have defined this singlet to be as reference set as zero.
Generally the other organic compounds show chemical shift downfield.So have positive chemical shift with respect to TMS shift.
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First, we shall calculate the total number of moles present in the final solution.
Number of moles in 0.50 m NaCl = molarity * volume = 0.50 * 3.0 = 1.5 moles.
Number of moles in 0.2777m NaCl = molarity * volume = 0.2777 * 9.0 = 0.24993 moles
Total number of moles = 1.5 + 0.24993 = 1.74993 moles
Second, we shall calculate the total volume of the final solution.
Total volume = 3 + 9 = 12 litres.
The molarity = total number of moles / total volume = 1.74993 / 12 = 0.1458 m