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Maurinko [17]
1 year ago
7

Be sure to answer all parts. what are the concentrations of hso4−, so42−, and h in a 0. 31 m khso4 solution? (hint: h2so4 is a s

trong acid; ka for hso4− = 1. 3 × 10−2. ) [hso4−] = m [so42−] = m [h ] = m
Chemistry
1 answer:
disa [49]1 year ago
3 0

At equilibrium the concentrations of:

[HSO₄⁻] = 0.10 M;

[SO₄²⁻] = 0.037 M;

[H⁺] = 0.037 M;

There is initially very little H+ and no SO₄²⁻ in the solution. A salt is KHSO₄⁻. All KHSO₄⁻ will split apart into K⁺ and HSO₄⁻ ions. [HSO₄⁻] will initially be present at a concentration of 0.14 M.

HSO₄⁻ will not gain H⁺ to produce H₂SO₄ since H₂SO₄ is a strong acid.  HSO₄⁻ may act as an acid and lose H⁺ to form SO₄²⁻. Let the final H⁺ concentration be x M. Construct a RICE table for the dissociation of HSO₄²⁻.

R   HSO_4^-    ⇄  H^+ + SO_4^2^-

I    0.14

C   - x               +x       +x

E   0.14-x        x         x

K_a = 1.3 × 10^-^2 for HSO^-_4 . As a result,

\frac{[H^+]. [SO_4^2^-]}{HSO_4^-} = K_a

K_a is large. It is no longer valid to approximate that [HSO^-_4] at equilibrium is the same as its initial value.

\frac{x^2}{0.14-y} = 1.3 * 10^-^2

x^2+1.3*10^-^2x - 0.14 × 1.3 × 10^-^2= 0

Solving the quadratic equation for x , x \geq 0 since x represents a concentration;

                             x=0.0366538

Then, round the results to 2 significant figure;

  • [SO_4^2^-] = x = 0.037 mol. L ^-^1
  • [H^+] = x = 0.037 mol. L ^-^1
  • [HSO_4^-] = 0.14 - x = 0.10 mol. L ^-^1

Learn more about concentration here:

brainly.com/question/14469428

#SPJ4

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