The best and most correct answer among the choices provided by your question is the second choice or letter B.
<span>Regarding the second electron affinity for an oxygen, i. e., the electron affinity for O-, it is much larger and negative.</span>
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Answer:
Option D. 3, 1, 3, 1 
Explanation:
From the question given above,
HNO₃ + Al(OH)₃ —> HOH + Al(NO₃)₃
The equation can be balance as follow:
HNO₃ + Al(OH)₃ —> HOH + Al(NO₃)₃
There are 3 atoms of N on the right side and 1 atom on the left side. It can be balance by 3 in front of HNO₃ as shown below:
3HNO₃ + Al(OH)₃ —> HOH + Al(NO₃)₃
There are a total of 6 atoms of H on the left side and 2 atoms on the right side. It can be balance by 3 in front of HOH as shown below:
3HNO₃ + Al(OH)₃ —> 3HOH + Al(NO₃)₃
Now, the equation is balanced. 
Thus, the coefficients are 3, 1, 3, 1 
 
        
             
        
        
        
Difference between Gas and Vapour:
                                                          
Gas: 
        A thermodynamic state in which a substance exists only in one phase i.e. Gas phase. In above given examples N₂, He and CO₂ exists as gases at room temperature. These gases cannot form a solid or liquid phase along with gas phase as these states requires very low temperatures.
Vapours: 
               It is a thermodyanamic state in which a substance exists in more than one phase. In given options Sulfur can exist in vapor state. This is because sulfur exists in a cyclic or chain form due to catenation (self linkage property). Therefore, a lower members of S allotrops can form a vapours.
        
             
        
        
        
<span>Well it depends on percentage by what, but I'll just assume that it's percentage by mass.
For this, we look at the atomic masses of the elements present in the compound.
Cu has an atomic mass of 63.546 amu
Fe has 55.845 amu
and S has 36.065 amu
Since there are 2 molecules of Sulfur for each one of Cu and Fe, we'll multiply the Sulfur atomic weight by 2 to obtain 72.13 amu
So we have not established the mass of the compound in amus
63.546 + 55.845 + 72.13 = 191.521
That is the atomic mass of Chalcopyrite. and Iron's atomic mass is 55.845
So to get the percentage, or fraction of iron, we take 55.845 / 191.521
Which comes out to 29.15% by mass
Mass of the sample is not needed for this calculation, but since the question mentions it I would go ahead and check if the question isn't also asking for the mass of Iron in the sample as well, in which case you just find the 29.15% of 67.7g</span>