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german
2 years ago
14

Why are thiols more nucleophilic than alcohols?

Chemistry
2 answers:
Nesterboy [21]2 years ago
6 0

Answer:

Sulfur is a bigger atom than oxygen and has a lower electgronegativity value. Therefore, the lone pair availability in thiol is higher than alcohol

Explanation:

Roman55 [17]2 years ago
4 0

Answer:

Thiols contain stronger acids than alcohols

Explanation:

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Given the equation C3H8(g) + O2(g) = CO2(g) + H2O(g) and that the enthalpies of formation for H2O(g) = -241.8 kJ/mol, CO2(g) = -
kari74 [83]

Answer: 72.4 kJ/mol

Explanation:

The balanced chemical reaction is,

C_3H_8(g)+5O_2(g)\rightarrow 3CO_2(g)+4H_2O(l)  \Delta H=-2220.1kJ/mol

The expression for enthalpy change is,

\Delta H=\sum [n\times \Delta H_f(product)]-\sum [n\times \Delta H_f(reactant)]

\Delta H=[(n_{CO_2}\times \Delta H_{CO_2})+(n_{H_2O}\times \Delta H_{H_2O})]-[(n_{O_2}\times \Delta H_{O_2})+(n_{C_3H_8}\times \Delta H_{C_3H_8})]

where,

n = number of moles

\Delta H_{O_2}=0 (as heat of formation of substances in their standard state is zero

Now put all the given values in this expression, we get

-2220.1=[(3\times -393.5)+(4\times -241.8)]-[(5\times 0)+(1\times \Delta H_{C_3H_8})]

\Delta H_{C_3H_8}=72.4kJ/mol

Therefore, the heat of formation of propane is 72.4 kJ/mol

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The location of four different fossils in the layers of a rock are listed below. Fossil A: Second layer from top Fossil B: Third
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Fossil C is the youngest. Layers further down were placed earlier than others. Because C is on the top layer, it must be the youngest (unless a disaster mixed up all the layers!).
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