Answer:
cis-1-tert-butyl-3-methylcyclohexane will have a higher percentage of the diequatorial-substituted conformer when compared with the diaxialsubstituted conformer.
Explanation:
The two compound contain or have high stability with the substituent group is at equatorial position but the tert-betyl group in cis-1-tert-butyl-3-methylcyclohexane is larger than the methyl group in trans-1,4-dimethylcyclohexane.
Thus, the equatorial position will be more favorable for the substituent group in the cis-1-tert-butyl-3-methylcyclohexane, therefore having higher percentage of the diequatorial substituted conformer compared with that of diaxial-substituted conformer.
Answer:
Clavulanic acid has two (2) chiral centers.
Explanation:
A chiral center is a center (usually carbon) with four different substituents.
The structure of clavulanic acid is shown in the attachment below.
Consider the labeled diagram in the attachment,
Carbon A is not a chiral carbon because it has two hydrogen atoms attached to it
Carbon B is not a chiral carbon because it has only three substituents
Carbon C is a chiral carbon because it has four different substituents
Carbon D is a chiral carbon because it has four different substituents
Carbon E is not a chiral carbon because it has only three atoms directly attached to it
Carbon F is not a chiral carbon because it has only three atoms directly attached to it
Carbon G is not a chiral carbon because it has two hydrogen atoms attached to it
Carbon H is not a chiral carbon because it has only three substituents
Then, only carbons C and D are chiral carbons.
Hence, clavulanic acid have two (2) chiral centers.
Because during combustion reaction, heat energy is released and it's this energy that is converted to work
Answer:
1380 kilogram/cubic meter
Answer: CoBr3 < K2SO4 < NH4 Cl
Justification:
1) The depression of the freezing point of a solution is a colligative property, which means that it depends on the number of particles of solute dissolved.
2) The formula for the depression of freezing point is:
ΔTf = i * Kf * m
Where i is the van't Hoof factor which accounts for the dissociation of the solute.
Kf is the freezing molal constant and only depends on the solvent
m is the molality (molal concentration).
3) Since, you are assuming equal concentrations and complete dissociation of the given solutes, the solute with more ions in the molecular formula will result in the solution with higher depression of the freezing point (lower freezing point).
4) These are the dissociations of the given solutes:
a) NH4 Cl (s) --> NH4(+)(aq) + Cl(-) (aq) => 1 mol --> 2 moles
b) Co Br3 (s) --> Co(3+) (aq) + 3Br(-)(aq) => 1 mol --> 4 moles
c) K2SO4 (s) --> 2K(+) (aq) + SO4 (2-) (aq) => 1 mol --> 3 moles
5) So, the rank of solutions by their freezing points is:
CoBr3 < K2SO4 < NH4 Cl
