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2 years ago

What is a common reason for observing an increased chemical shift of a c-h proton

1 answer:

3 0

Deshielding due to an electronegative element close by is the common reason for observing increased chemical shift of a c-h proton

<h3>What is a chemical shift? </h3>

The resonance frequency of a proton in relation to a standard compound is represented by chemical shift. Chemical shift, which is measured in ppm and is represented by the sign (δ), (parts per million).The chemical shift in a proton NMR spectrum provides details about the targeted proton's chemical surroundings. The structure of the investigated substance, especially electronegative components or effects, has a significant impact on the chemical shift value. Electronegative elements' ability to remove electron density from the proton, which raises the chemical shift value, is one explanation for this. The proton is more exposed to the magnetic field that is being applied externally as a result of this process, which is referred to as de-shielding.

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Determine the molar mass of a 0.458-gram sample of gas having a volume of 1.20 l at 287 k and 0.980 atm. group of answer choices

lilavasa [31]

Considering the ideal gas law and the definition of molar mass, the molar mass of the sample of gas is 9.17 $\frac{g}{mol}$ .

<h3>Ideal gas law</h3>

An ideal gas is a theoretical gas that is considered to be composed of randomly moving point particles that do not interact with each other. Gases in general are ideal when they are at high temperatures and low pressures.

The pressure, P, the temperature, T, and the volume, V, of an ideal gas, are related by a simple formula called the ideal gas law:

P×V = n×R×T

where:

P is the gas pressure.
V is the volume that occupies.
T is its temperature.
R is the ideal gas constant. The universal constant of ideal gases R has the same value for all gaseous substances.
n is the number of moles of the gas.

<h3>Definition of molar mass</h3>

The molar mass of substance is a property defined as its mass per unit quantity of substance, in other words, molar mass is the amount of mass that a substance contains in one mole.

<h3>Molar mass of the sample of gas</h3>

In this case you know:

P= 0.980 arm
V= 1.20 L
T= 287 K
R= 0.082 $\frac{atmL}{molK}$
n= ?

Replacing in the ideal gas law:

0.980 atm× 1.20 L= n× 0.082 $\frac{atmL}{molK}$ × 287 K

Solving:

(0.980 atm× 1.20 L)÷ (0.082 $\frac{atmL}{molK}$ × 287 K)= n

<u><em>0.04997 moles= n</em></u>

On the other hand, you know that the<u><em> mass of the sample of gas</em></u> is <u><em>0.458 grams</em></u>. Replacing in the definition of molar mass:

$molar mass=\frac{0.458 grams}{0.04997 moles}$

Solving:

<u><em>molar mass= 9.17 </em></u> $\frac{g}{mol}$

Finally, the molar mass of the sample of gas is 9.17 $\frac{g}{mol}$ .

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6 0

2 years ago

An equimolar mixture of acetone and ethanol is fed to an evacuated vessel and allowedto come to equilibrium at 65°C and 1.00 atm

frutty [35]

The question is incomplete, the table of the question is given below

Answer:

I) xA= 0.34, yA= 0.55

ii) 76.2 mole % vapor

iii) Percentage of vapor volume = 98%

Explanation:

i) xA= 0.34, yA= 0.55

xA= 0.34, yA= 0.55

ii) 0.50 = 0.55 nv + 0.34 nL

Therefore, nV = 0.762 mol vapor and nL = 0.238 mol liquid

This shows 76.2 mole % vapor

iii) ρA= 0.791 g/cm3 and, ρE = 0.789 g/cm3

Therefore, ρ = 0.790 g/cm3

Now, we have:

MA = 58.08 g/mol and ME= 46.07 g/mol

So Ml = (0.34 x 58.08)+[(1 -0.34) x 46.07] = 50.15 g/mol

1 mol liquid = (0.762 mol vapor/0.238 mol liquid) = 3.2 mol vapor

Liquid volume = Vl= [1 mol x (50.15 g/mol)] / (0.790 g/cm3) = 63.48 cm3

Vapour volume = Vv = 3.2 mol x(22400 cm3/mol) x [(65+273)/273] = 88747 cm3

Therefore, percentage of vapour volume = 88747 / (88747+63.48) = 99.9 %

3 0

3 years ago

What happened during the Renaissance that encouraged progress in the study of matter?

lukranit [14]

During the dark ages-All that wasn't around the christian religion were lost. Knowledge and discoveries before the Dark Ages were mainly in Greek ideas. Biblic scripts however were in Latin. Therefore all inventions up to the dark ages were lost and only religious scripts preserved in the churches. Outside the church, no one knew how to write, read or even communicate.

5 0

3 years ago

NAME the four phases of matter and DESCRIBE how the intermolecular forces and kinetic energy change as you change phases.

weqwewe [10]

Answer: Substances on Earth can exist in one of four phases, but mostly, they exist in one of three: solid, liquid or gas. Learn the six changes of phase: freezing, melting, condensation, vaporization, sublimation and deposition. Intermolecular forces are forces between molecules that determine the physical properties of liquids and solids. 11.2 Vaporization and Vapor Pressure— vaporization is the conversion of a liquid to a gas (vapor), and the quantity of heat associated with this phase change is known as the enthalpy (heat) of vaporization. When kinetic energy is increasing molecules are simply moving faster. However, when the potential energy is increasing molecules are changing phases. Therefore, when the potential energy is increasing is when the molecule is changing phases. Phase changes require either the addition of heat energy (melting, evaporation, and sublimation) or subtraction of heat energy (condensation and freezing). ... Changing the amount of heat energy usually causes a temperature change.

HOpe this helps..... Stay safe and have a Merry Christmas!!!!!!!!!! :D

5 0

2 years ago

Magnesium (Mg) has an atomic number of 12. What is the ground-state electron configuration of magnesium?

Brums [2.3K]

C. 12222632

You have to follow the Aufbau principle, which states that electrons populate the atomic orbitals situated at the lowest energy first.

The orbitals are:

333

4444

5555

666

4 0

3 years ago

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