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alexandr402 [8]
1 year ago
8

What is a common reason for observing an increased chemical shift of a c-h proton

Chemistry
1 answer:
stira [4]1 year ago
3 0

Deshielding due to an electronegative element close by is the common reason for observing increased chemical shift of a c-h proton

<h3>What is a chemical shift? </h3>

The resonance frequency of a proton in relation to a standard compound is represented by chemical shift. Chemical shift, which is measured in ppm and is represented by the sign (δ),  (parts per million).The chemical shift in a proton NMR spectrum provides details about the targeted proton's chemical surroundings. The structure of the investigated substance, especially electronegative components or effects, has a significant impact on the chemical shift value. Electronegative elements' ability to remove electron density from the proton, which raises the chemical shift value, is one explanation for this. The proton is more exposed to the magnetic field that is being applied externally as a result of this process, which is referred to as de-shielding.

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a flask was filled with SO2 at a partial pressure of 0.409 atm and O2 at a partial pressure of 0.601 atm. The following gas-phas
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Answer:

The equilibrium partial pressure of O2 is 0.545 atm

Explanation:

Step 1: Data given

Partial pressure of SO2 = 0.409 atm

Partial pressure of O2 = 0.601 atm

At equilibrium, the partial pressure of SO2 was 0.297 atm.

Step 2: The balanced equation

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Step 3: The initial pressure

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pO2 = 0.601 atm

pSO3 = 0 atm

Step 4: Calculate the pressure at the equilibrium

pSO2 = 0.409 - 2X atm

pO2 = 0.601 - X atm

pSO3 = 2X

pSO2 = 0.409 - 2X atm = 0.297

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pSO3 = 2*0.056 = 0.112 atm

Step 5: Calculate Kp

Kp = (pSO3)²/((pO2)*(pSO2)²)

Kp = (0.112²) / (0.545 * 0.297²)

Kp = 0.261

The equilibrium partial pressure of O2 is 0.545 atm

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